CHEBI:145019 - rebaudioside M

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ChEBI Name rebaudioside M
ChEBI ID CHEBI:145019
Definition A rebaudioside that is rebaudioside A in which the the hydroxy groups at positions 2 and 3 of the β-D-glucosyl ester moiety have both been converted to the corresponding β-D-glucoside. Found in very low concentraitions in the leaves of Stevia Rebaudiana, it is more than 200 times sweeter than sucrose.
Stars This entity has been manually annotated by the ChEBI Team.
Submitter Kristian Axelsen
Supplier Information
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Formula C56H90O33
Net Charge 0
Average Mass 1291.303
Monoisotopic Mass 1290.53644
InChI InChI=1S/C56H90O33/c1-19-11-55-9-5-26-53(2,7-4-8-54(26,3)52(77)88-50-44(86-48-40(75)36(71)30(65)22(14-59)80-48)42(32(67)24(16-61)82-50)84-46-38(73)34(69)28(63)20(12-57)78-46)27(55)6-10-56(19,18-55)89-51-45(87-49-41(76)37(72)31(66)23(15-60)81-49)43(33(68)25(17-62)83-51)85-47-39(74)35(70)29(64)21(13-58)79-47/h20-51,57-76H,1,4-18H2,2-3H3/t20-,21-,22-,23-,24-,25-,26+,27+,28-,29-,30-,31-,32-,33-,34+,35+,36+,37+,38-,39-,40-,41-,42+,43+,44-,45-,46+,47+,48+,49+,50+,51+,53-,54-,55-,56+/m1/s1
InChIKey GSGVXNMGMKBGQU-PHESRWQRSA-N
SMILES [C@]123[C@]([C@]4([C@@]([C@](CCC4)(C)C(O[C@@H]5O[C@@H]([C@@H](O)[C@@H]([C@H]5O[C@@H]6O[C@@H]([C@@H](O)[C@@H]([C@H]6O)O)CO)O[C@@H]7O[C@@H]([C@@H](O)[C@@H]([C@H]7O)O)CO)CO)=O)(CC1)[H])C)(CC[C@@](C2)(O[C@H]8[C@H](O[C@@H]9O[C@@H]([C@@H](O)[C@@H]([C@H]9O)O)CO)[C@H]([C@H](O)[C@H](O8)CO)O[C@@H]%10O[C@@H]([C@@H](O)[C@@H]([C@H]%10O)O)CO)C(C3)=C)[H]
Roles Classification
Biological Role(s): sweetening agent
Substance that sweeten food, beverages, medications, etc.
(via steviol glycoside )
plant metabolite
Any eukaryotic metabolite produced during a metabolic reaction in plants, the kingdom that include flowering plants, conifers and other gymnosperms.
(via rebaudioside )
Application(s): sweetening agent
Substance that sweeten food, beverages, medications, etc.
(via steviol glycoside )
View more via ChEBI Ontology
ChEBI Ontology
Outgoing rebaudioside M (CHEBI:145019) has functional parent β-D-Glcp-(1→2)-[β-D-Glcp-(1→3)]-β-D-Glcp (CHEBI:146806)
rebaudioside M (CHEBI:145019) has functional parent rebaudioside A (CHEBI:145012)
rebaudioside M (CHEBI:145019) has functional parent rebaudioside D (CHEBI:145022)
rebaudioside M (CHEBI:145019) has role sweetening agent (CHEBI:50505)
rebaudioside M (CHEBI:145019) is a β-D-glucoside (CHEBI:22798)
rebaudioside M (CHEBI:145019) is a rebaudioside (CHEBI:145023)
IUPAC Name
β-D-glucopyranosyl-(1→2)-[β-D-glucopyranosyl-(1→3)]-1-O-(13α-{[β-D-glucopyranosyl-(1→2)-[β-D-glucopyranosyl-(1→3)]-β-D-glucopyranosyl]oxy}-18-oxo-5β,8α,9β,10α-kaur-16-en-18-yl)-β-D-glucopyranose
Synonyms Sources
Reb M ChEBI
Reb X ChEBI
Reb-M ChEBI
Reb-X ChEBI
rebaudioside M UniProt
rebaudioside X ChEBI
Registry Number Type Source
1220616-44-3 CAS Registry Number ChEBI
Citations Waiting for Citations Types Sources
24361573 PubMed citation Europe PMC
24424316 PubMed citation Europe PMC
24758242 PubMed citation Europe PMC
27923373 PubMed citation Europe PMC
28234311 PubMed citation Europe PMC
31279071 PubMed citation Europe PMC
31324778 PubMed citation SUBMITTER
Last Modified
06 March 2024