CHEBI:67469 - 15-hydroxyajubractin C

Main ChEBI Ontology Automatic Xrefs Reactions Pathways Models
ChEBI Name 15-hydroxyajubractin C
ChEBI ID CHEBI:67469
Definition A diterpenoid isolated from the aerial parts of Ajuga bracteosa.
Stars This entity has been manually annotated by the ChEBI Team.
Supplier Information
Download Molfile XML SDF
Formula C29H44O10
Net Charge 0
Average Mass 552.65370
Monoisotopic Mass 552.29345
InChI InChI=1S/C29H44O10/c1-7-15(2)25(33)37-21-9-8-20-27(6,22-11-19-12-24(32)39-26(19)38-22)16(3)10-23(36-18(5)31)28(20,13-34-17(4)30)29(21)14-35-29/h15-16,19-24,26,32H,7-14H2,1-6H3/t15?,16-,19+,20-,21+,22+,23+,24?,26-,27+,28+,29-/m1/s1
InChIKey RZHRFYOKQJTDFE-RAHYLWCHSA-N
SMILES CCC(C)C(=O)O[C@H]1CC[C@@H]2[C@@](C)([C@@H]3C[C@H]4CC(O)O[C@H]4O3)[C@H](C)C[C@H](OC(C)=O)[C@@]2(COC(C)=O)[C@@]11CO1
Metabolite of Species Details
Ajuga bracteosa (IPNI:444535-1) Found in aerial part (BTO:0001658). Crude dichloromethane extract of dried and powdered aerial parts, C-15 epimeric mixture See: PubMed
Roles Classification
Biological Role(s): plant metabolite
Any eukaryotic metabolite produced during a metabolic reaction in plants, the kingdom that include flowering plants, conifers and other gymnosperms.
Application(s): antifeedant
A substance that prevents pests from feeding.
View more via ChEBI Ontology
ChEBI Ontology
Outgoing 15-hydroxyajubractin C (CHEBI:67469) has role antifeedant (CHEBI:22583)
15-hydroxyajubractin C (CHEBI:67469) has role plant metabolite (CHEBI:76924)
15-hydroxyajubractin C (CHEBI:67469) is a acetate ester (CHEBI:47622)
15-hydroxyajubractin C (CHEBI:67469) is a cyclic acetal (CHEBI:59770)
15-hydroxyajubractin C (CHEBI:67469) is a diterpenoid (CHEBI:23849)
15-hydroxyajubractin C (CHEBI:67469) is a furofuran (CHEBI:47790)
15-hydroxyajubractin C (CHEBI:67469) is a spiro-epoxide (CHEBI:133131)
IUPAC Name
(1R,2S,4aR,5S,6R,8S,8aR)-8-(acetyloxy)-8a-[(acetyloxy)methyl]-5-[(2S,3aS,6aR)-5-hydroxyhexahydrofuro[2,3-b]furan-2-yl]-5,6-dimethyloctahydro-2H-spiro[naphthalene-1,2'-oxiran]-2-yl 2-methylbutanoate
Citation Waiting for Citations Type Source
21539300 PubMed citation Europe PMC
Last Modified
24 August 2016