CHEBI:60539 - Mo(=O)-bis(molybdopterin guanine dinucleotide)(4−)

Main ChEBI Ontology Automatic Xrefs Reactions Pathways Models
ChEBI Name Mo(=O)-bis(molybdopterin guanine dinucleotide)(4−)
ChEBI ID CHEBI:60539
ChEBI ASCII Name Mo(=O)-bis(molybdopterin guanine dinucleotide)(4-)
Definition An organophosphate oxoanion arising from deprotonation of the diphosphate OH groups of molybdate-bis(molybdopterin guanine dinucleotide); major species at pH 7.3.
Stars This entity has been manually annotated by the ChEBI Team.
Submitter Kristian Axelsen
KAX
Secondary ChEBI IDs CHEBI:71312
Supplier Information
Download Molfile XML SDF
more structures >>
Formula C40H44MoN20O27P4S4
Net Charge -4
Average Mass 1584.990
Monoisotopic Mass 1585.95941
InChI InChI=1S/2C20H26N10O13P2S2.Mo.O/c2*21-19-26-13-7(15(33)28-19)24-6-12(47)11(46)5(41-17(6)25-13)2-40-45(37,38)43-44(35,36)39-1-4-9(31)10(32)18(42-4)30-3-23-8-14(30)27-20(22)29-16(8)34;;/h2*3-6,9-10,17-18,24,31-32,46-47H,1-2H2,(H,35,36)(H,37,38)(H3,22,27,29,34)(H4,21,25,26,28,33);;/q;;+4;/p-8/t2*4-,5-,6+,9-,10-,17-,18-;;/m11../s1
InChIKey SPLYCLQDZVSNSU-HWCCSRDCSA-F
SMILES [H][C@]12NC3=C(N[C@@]1([H])C1=C(S[Mo]4(=O)(SC5=C(S4)[C@]4([H])NC6=C(N[C@]4([H])O[C@@H]5COP([O-])(=O)OP([O-])(=O)OC[C@H]4O[C@H]([C@H](O)[C@@H]4O)N4C=NC5=C4N=C(N)NC5=O)N=C(N)NC6=O)S1)[C@@H](COP([O-])(=O)OP([O-])(=O)OC[C@H]1O[C@H]([C@H](O)[C@@H]1O)N1C=NC4=C1N=C(N)NC4=O)O2)C(=O)NC(N)=N3
Roles Classification
Biological Role(s): Escherichia coli metabolite
Any bacterial metabolite produced during a metabolic reaction in Escherichia coli.
(via Mo-molybdopterin cofactor )
cofactor
An organic molecule or ion (usually a metal ion) that is required by an enzyme for its activity. It may be attached either loosely (coenzyme) or tightly (prosthetic group).
(via molybdopterin cofactor )
View more via ChEBI Ontology
ChEBI Ontology
Outgoing Mo(=O)-bis(molybdopterin guanine dinucleotide)(4−) (CHEBI:60539) is a Mo-molybdopterin cofactor (CHEBI:21437)
Mo(=O)-bis(molybdopterin guanine dinucleotide)(4−) (CHEBI:60539) is a organophosphate oxoanion (CHEBI:58945)
Mo(=O)-bis(molybdopterin guanine dinucleotide)(4−) (CHEBI:60539) is conjugate base of Mo(=O)-bis(molybdopterin guanine dinucleotide) (CHEBI:22894)
Incoming Mo(=O)-bis(molybdopterin guanine dinucleotide) (CHEBI:22894) is conjugate acid of Mo(=O)-bis(molybdopterin guanine dinucleotide)(4−) (CHEBI:60539)
IUPAC Name
bis{5'-O-[{[{[(5aR,8R,9aR)-2-amino-4-oxo-6,7-bis(sulfanyl-κS)-3,5,5a,8,9a,10-hexahydro-4H-pyrano[3,2-g]pteridin-8-yl]methoxy}(hydroxy)phosphoryl]oxy}(hydroxy)phosphoryl]guanosinato(4−)}(oxido)molybdate(4−)
Synonyms Sources
Mo(=O)-bis(molybdopterin guanine dinucleotide) tetraanion ChEBI
Mo-bis(molybdopterin guanine dinucleotide) UniProt
molybdate-bis(molybdopterin guanine dinucleotide) tetraanion ChEBI
Manual Xref Database
CPD-15873 MetaCyc
View more database links
Citations Waiting for Citations Types Sources
11250197 PubMed citation SUBMITTER
24003231 PubMed citation Europe PMC
Last Modified
05 June 2024