All rules > rule id: 802431

Reaction SMARTS

[#6+0:1](-[#8-:2])(=[#8+0:3])-[#6,#1;+0:4].[#8+0:5](-[#1+0:6])-[#1+0:7].[#6+0:8]-[#8+0:9]-[#6+0:14](-[#6+0:10](-[#6,#1;+0:11])(-[#8+0:12])-[#1,#6;+0:13])(-[#8+0:15]-[#6+0:16](-[#6,#1;+0:17])=[#8+0:18])-[#1+0:19]>>[#6+0:1](-[#8+0:2]-[#1+0:6])(=[#8+0:3])-[#6,#1;+0:4].[#8+0:5](-[#1+0:7])-[#6+0:14](-[#8+0:9]-[#6+0:8])(-[#6+0:10](-[#6,#1;+0:11])(-[#8+0:12])-[#1,#6;+0:13])-[#1+0:19].[#8-:15]-[#6+0:16](-[#6,#1;+0:17])=[#8+0:18]

Simplified SMARTS

C([O-])(=O)*.O([H])[H].COC(C(*)(O)*)(OC(*)=O)[H]>>C(O[H])(=O)*.O([H])C(OC)(C(*)(O)*)[H].[O-]C(*)=O

Rule Set Version: 0.2
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Complete rule seen in 10 catalytic steps

m-csa:285 - oligo-1,6-glucosidase - mechanism: 1 - step: 2
m-csa:397 - alpha-amylase - mechanism: 2 - step: 2
m-csa:560 - cellulase (GH12) - mechanism: 1 - step: 2
m-csa:580 - glucan endo-1,3-beta-D-glucosidase - mechanism: 1 - step: 4
m-csa:658 - arabinogalactan endo-1,4-beta-galactosidase - mechanism: 1 - step: 2
m-csa:764 - glucosylceramidase - mechanism: 1 - step: 3
m-csa:793 - mannosyl-oligosaccharide 1,3-1,6-alpha-mannosidase - mechanism: 1 - step: 4
m-csa:793 - mannosyl-oligosaccharide 1,3-1,6-alpha-mannosidase - mechanism: 1 - step: 2
m-csa:831 - glucan 1,3-beta-glucosidase - mechanism: 1 - step: 2
m-csa:976 - α‑glucosidase maltase-glucoamylase - mechanism: 1 - step: 2

Rule partially seen in 3 catalytic steps

m-csa:19 - mannosyl-oligosaccharide 1,2-alpha-mannosidase - mechanism: 1 - step: 1
m-csa:559 - cellulase (GH9) - mechanism: 1 - step: 1
m-csa:561 - cellulase (GH45) - mechanism: 1 - step: 1