All rules > rule id: 801363

Reaction SMARTS

[#8-:1]-[#6+0:2](=[#8+0:3])-[#6,#1;+0:4].[#6+0:5](-[#8+0:6])(-[#6+0:7](=[#8+0:8])-[#6+0:9](-[#8+0:10]-[#1+0:22])(-[#6+0:11](-[#6+0:15](-[#6,#1;+0:16])(-[#8+0:17])-[#1,#6;+0:18])(-[#8+0:19]-[#1+0:20])-[#1+0:21])-[#1+0:12])(-[#1,#6;+0:13])-[#1,#6;+0:14]>>[#8+0:1](-[#6+0:2](=[#8+0:3])-[#6,#1;+0:4])-[#1+0:20].[#6+0:5](-[#8+0:6])(-[#6+0:7](-[#8-:8])=[#6+0:9](-[#8+0:10]-[#1+0:22])-[#1+0:12])(-[#1,#6;+0:13])-[#1,#6;+0:14].[#6+0:11](-[#6+0:15](-[#6,#1;+0:16])(-[#8+0:17])-[#1,#6;+0:18])(=[#8+0:19])-[#1+0:21]

Simplified SMARTS

[O-]C(=O)*.C(O)(C(=O)C(O[H])(C(C(*)(O)*)(O[H])[H])[H])(*)*>>O(C(=O)*)[H].C(O)(C([O-])=C(O[H])[H])(*)*.C(C(*)(O)*)(=O)[H]

Rule Set Version: 0.2
→

Complete rule seen in 3 catalytic steps

m-csa:52 - fructose-bisphosphate aldolase (Class II) - mechanism: 1 - step: 2
m-csa:273 - L-ribulose-5-phosphate 4-epimerase - mechanism: 1 - step: 2
m-csa:645 - rhamnulose-1-phosphate aldolase - mechanism: 1 - step: 2

Rule partially seen in 8 catalytic steps

m-csa:72 - L-fuculose-phosphate aldolase - mechanism: 1 - step: 1
m-csa:95 - L-fucose isomerase - mechanism: 1 - step: 2
m-csa:148 - transaldolase (type I) - mechanism: 2 - step: 6
m-csa:148 - transaldolase (type I) - mechanism: 1 - step: 6
m-csa:148 - transaldolase (type I) - mechanism: 1 - step: 4
m-csa:222 - fructose-bisphosphate aldolase (Class I) - mechanism: 1 - step: 7
m-csa:351 - aldose 1-epimerase - mechanism: 1 - step: 2
m-csa:645 - rhamnulose-1-phosphate aldolase - mechanism: 1 - step: 3