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CHEBI:72675 - (+)-phytocassane E

ChEBI IDCHEBI:72675
ChEBI Name(+)-phytocassane E
Stars
DefinitionA phytocassane that is (+)-phytocassane C in which the hydroxy group at position 3 has been oxidised to the give corresponding ketone.
Last Modified11 January 2018
SubmitterSteve
DownloadsMolfile
FormulaC20H28O3
Net Charge0
Average Mass316.441
Monoisotopic Mass316.20384
SMILES[H][C@@]12C(=O)C=C(C=C)[C@@H](C)[C@@]1([H])CC[C@]1([H])C(C)(C)C(=O)C[C@H](O)[C@@]21C
InChIInChI=1S/C20H28O3/c1-6-12-9-14(21)18-13(11(12)2)7-8-15-19(3,4)16(22)10-17(23)20(15,18)5/h6,9,11,13,15,17-18,23H,1,7-8,10H2,2-5H3/t11-,13-,15-,17+,18+,20+/m1/s1
InChIKeyMMRGGLJWHXYKLZ-NEYRYYQWSA-N
Roles Classification
Biological Roles:
plant metabolite  Any eukaryotic metabolite produced during a metabolic reaction in plants, the kingdom that include flowering plants, conifers and other gymnosperms.
antifungal agent  An antimicrobial agent that destroys fungi by suppressing their ability to grow or reproduce.
phytoalexin  A toxin made by a plant that acts against an organism attacking it.
ChEBI Ontology
Outgoing Relation(s)
(+)-phytocassane E (CHEBI:72675) is a diketone (CHEBI:46640)
(+)-phytocassane E (CHEBI:72675) is a phytocassane (CHEBI:139395)
IUPAC Name 
1α-hydroxy-14β-methyl-13-vinyl-5β,8α,9β,10α-podocarp-12-ene-3,11-dione
Synonyms  Source
phytocassane EChEBI
ent-1β-hydroxy-12,15-cassadiene-3,11-dioneChEBI
(4S,4aR,4bR,8S,8aR,10aS)-7-ethenyl-4-hydroxy-1,1,4a,8-tetramethyl-1,3,4,4a,4b,8,8a,9,10,10a-decahydrophenanthrene-2,5-dioneIUPAC
(4S,4aR,4bR,8S,8aR,10aS)-4-hydroxy-1,1,4a,8-tetramethyl-7-vinyl-1,3,4,4a,4b,8,8a,9,10,10a-decahydrophenanthrene-2,5-dioneIUPAC
(1α,5β,8α,9β,10α,14β)-1-hydroxy-14-methyl-13-vinylpodocarp-12-ene-3,11-dioneIUPAC
Citations