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CHEBI:69377 - hermannioside A

ChEBI IDCHEBI:69377
ChEBI Namehermannioside A
Stars
DefinitionA quercetin O-glycoside that is quercetin attached to a α-L-rhamnopyranosyl residue at position 7 and a α-L-rhamnopyranosyl-(1→2)-α-L-arabinopyranosyl residue at position 3 via glycosidic linkages. It has been isolated from Anthyllis hermanniae.
Last Modified9 January 2014
DownloadsMolfile
FormulaC32H38O19
Net Charge0
Average Mass726.637
Monoisotopic Mass726.20073
SMILES[H][C@@]1(O[C@H]2[C@H](Oc3c(-c4ccc(O)c(O)c4)oc4cc(O[C@@H]5O[C@@H](C)[C@H](O)[C@@H](O)[C@H]5O)cc(O)c4c3=O)OC[C@H](O)[C@@H]2O)O[C@@H](C)[C@H](O)[C@@H](O)[C@H]1O
InChIInChI=1S/C32H38O19/c1-9-19(37)23(41)25(43)30(46-9)48-12-6-15(35)18-17(7-12)49-27(11-3-4-13(33)14(34)5-11)28(22(18)40)50-32-29(21(39)16(36)8-45-32)51-31-26(44)24(42)20(38)10(2)47-31/h3-7,9-10,16,19-21,23-26,29-39,41-44H,8H2,1-2H3/t9-,10-,16-,19-,20-,21-,23+,24+,25+,26+,29+,30-,31-,32-/m0/s1
InChIKeyNVNDXAJMMOSZAJ-VJAYFQCDSA-N
Species of MetaboliteComponentSourceComments
Anthyllis hermanniae (ncbitaxon:181246) whole plant (BTO:0001461) PubMed (21861458) Methanolic extract of air dried and powdered plant
Roles Classification
Biological Role:
plant metabolite  Any eukaryotic metabolite produced during a metabolic reaction in plants, the kingdom that include flowering plants, conifers and other gymnosperms.
ChEBI Ontology
Outgoing Relation(s)
hermannioside A (CHEBI:69377) has role plant metabolite (CHEBI:76924)
hermannioside A (CHEBI:69377) is a quercetin O-glycoside (CHEBI:76424)
hermannioside A (CHEBI:69377) is a trihydroxyflavone (CHEBI:27116)
hermannioside A (CHEBI:69377) is a α-L-rhamnoside (CHEBI:27848)
IUPAC Name 
3-{[2-O-(6-deoxy-α-L-mannopyranosyl)-α-L-arabinopyranosyl]oxy}-2-(3,4-dihydroxyphenyl)-5-hydroxy-4-oxo-4H-chromen-7-yl 6-deoxy-α-L-mannopyranoside
Synonym  Source
quercetin 3-O-[α-L-rhamnopyranosyl-(1→2)-α-L-arabinopyranoside]-7-O-α-L-rhamnopyranosideChEBI
Registry NumbersSources
Reaxys:21897855Reaxys
Citations