All rules > rule id: 805335

Reaction SMARTS

[#6+0:1](-[#6,#1;+0:2])(-[#1,#6;+0:3])(-[#1,#6;+0:4])-[#6+0:5](-[#6+0:6](-[#1,#6;+0:7])(-[#1,#6;+0:8])-[#1,#6;+0:9])=[#6+0:10](-[#6+:11](-[#1+0:12])-[#1+0:13])-[#1+0:14].[#8-:15]-[#15+0:16](-[#8+0:17])(=[#8+0:18])-[#8-:19]>>[#6+0:1](-[#6,#1;+0:2])(-[#1,#6;+0:3])(-[#1,#6;+0:4])-[#6+0:5](-[#6+0:6](-[#1,#6;+0:7])(-[#1,#6;+0:8])-[#1,#6;+0:9])(-[#6+0:10](=[#6+0:11](-[#1+0:12])-[#1+0:13])-[#1+0:14])-[#8+0:15]-[#15+0:16](-[#8+0:17])(=[#8+0:18])-[#8-:19]

Simplified SMARTS

C(*)(*)(*)C(C(*)(*)*)=C([C+]([H])[H])[H].[O-]P(O)(=O)[O-]>>C(*)(*)(*)C(C(*)(*)*)(C(=C([H])[H])[H])OP(O)(=O)[O-]

Rule Set Version: 0.2
→

Complete rule seen in 3 catalytic steps

m-csa:259 - bornyl diphosphate synthase - mechanism: 1 - step: 2
m-csa:262 - trichodiene synthase - mechanism: 1 - step: 3
m-csa:263 - epi-isozizaene synthase - mechanism: 1 - step: 3

Rule partially seen in 0 catalytic steps