All rules > rule id: 803386

Reaction SMARTS

[#6+0:1](-[#8+0:2]-[#1+0:11])(=[#8+0:3])-[#6,#1;+0:4].[#6+0:5](-[#6,#1;+0:6])(-[#1,#6;+0:7])(-[#1,#6;+0:8])-[#7+:9](-[#1+0:10])(-[#1+0:12])-[#1+0:13].[#8+0:14]=[#6+0:15](-[#6+0:17](-[#6,#1;+0:18])(-[#1,#6;+0:19])-[#1,#6;+0:20])-[#6+0:21](-[#8-:22])=[#8+0:23].[#1+0:16]-[#6+0:32]1(-[#6+0:31](=[#6+0:29](-[#7+0:27](-[#6+0:25](-[#8+0:24])(-[#6,#1;+0:26])-[#1,#6;+0:36])-[#6+0:28](=[#6+0:33]-1-[#6+0:34](=[#8+0:39])-[#7+0:40])-[#1+0:35])-[#1,#6;+0:30])-[#1,#6;+0:37])-[#1+0:38]>>[#6+0:1](-[#8-:2])(=[#8+0:3])-[#6,#1;+0:4].[#6+0:5](-[#6,#1;+0:6])(-[#1,#6;+0:7])(-[#1,#6;+0:8])-[#7+:9](-[#1+0:10])(-[#1+0:11])-[#1+0:12].[#1+0:13]-[#8+0:14]-[#6+0:15](-[#1+0:16])(-[#6+0:17](-[#6,#1;+0:18])(-[#1,#6;+0:19])-[#1,#6;+0:20])-[#6+0:21](-[#8-:22])=[#8+0:23].[#8+0:24]-[#6+0:25](-[#6,#1;+0:26])(-[#7+:27]1=[#6+0:28](-[#6+0:33](=[#6+0:32](-[#6+0:31](=[#6+0:29]-1-[#1,#6;+0:30])-[#1,#6;+0:37])-[#1+0:38])-[#6+0:34](=[#8+0:39])-[#7+0:40])-[#1+0:35])-[#1,#6;+0:36]

Simplified SMARTS

C(O[H])(=O)*.C(*)(*)(*)[N+]([H])([H])[H].O=C(C(*)(*)*)C([O-])=O.[H]C1([H])C(*)=C(*)N(C(O)(*)*)C([H])=C1C(=O)N>>C([O-])(=O)*.C(*)(*)(*)[N+]([H])([H])[H].[H]OC([H])(C(*)(*)*)C([O-])=O.OC(*)([N+]1=C([H])C(C(=O)N)=C([H])C(*)=C1*)*

Rule Set Version: 0.2
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Complete rule seen in 2 catalytic steps

m-csa:7 - isocitrate dehydrogenase (NADP+) - mechanism: 2 - step: 1
m-csa:21 - malate dehydrogenase (oxaloacetate-decarboxylating) - mechanism: 1 - step: 1

Rule partially seen in 41 catalytic steps

m-csa:7 - isocitrate dehydrogenase (NADP+) - mechanism: 1 - step: 1
m-csa:7 - isocitrate dehydrogenase (NADP+) - mechanism: 3 - step: 2
m-csa:59 - 3-dehydroquinate synthase - mechanism: 1 - step: 1
m-csa:67 - alanine dehydrogenase - mechanism: 1 - step: 1
m-csa:90 - adenosylhomocysteinase - mechanism: 1 - step: 2
m-csa:92 - UDP-glucose 6-dehydrogenase - mechanism: 2 - step: 1
m-csa:92 - UDP-glucose 6-dehydrogenase - mechanism: 1 - step: 3
m-csa:92 - UDP-glucose 6-dehydrogenase - mechanism: 1 - step: 1
m-csa:92 - UDP-glucose 6-dehydrogenase - mechanism: 2 - step: 3
m-csa:100 - betaine-aldehyde dehydrogenase - mechanism: 1 - step: 2
m-csa:116 - NAD(P)+ transhydrogenase (AB-specific) - mechanism: 1 - step: 2
m-csa:188 - UDP-glucose 4-epimerase - mechanism: 2 - step: 1
m-csa:188 - UDP-glucose 4-epimerase - mechanism: 1 - step: 1
m-csa:226 - UDP-sulfoquinovose synthase - mechanism: 1 - step: 1
m-csa:228 - dTDP-glucose 4,6-dehydratase - mechanism: 1 - step: 1
m-csa:228 - dTDP-glucose 4,6-dehydratase - mechanism: 2 - step: 1
m-csa:255 - alcohol dehydrogenase (SDR type) - mechanism: 1 - step: 2
m-csa:256 - alcohol dehydrogenase (class I) - mechanism: 1 - step: 1
m-csa:312 - glycerol dehydrogenase - mechanism: 1 - step: 1
m-csa:331 - inositol-3-phosphate synthase - mechanism: 1 - step: 1
m-csa:336 - L-3-hydroxyacyl-CoA dehydrogenase - mechanism: 1 - step: 2
m-csa:526 - malate dehydrogenase (type 2) - mechanism: 1 - step: 1
m-csa:527 - malate dehydrogenase (type 1) - mechanism: 1 - step: 1
m-csa:557 - ADP-glyceromanno-heptose 6-epimerase - mechanism: 2 - step: 1
m-csa:557 - ADP-glyceromanno-heptose 6-epimerase - mechanism: 1 - step: 1
m-csa:576 - D-lactate dehydrogenase - mechanism: 1 - step: 1
m-csa:579 - glutamate dehydrogenase - mechanism: 1 - step: 1
m-csa:584 - L-lactate dehydrogenase - mechanism: 1 - step: 1
m-csa:593 - glycerol-3-phosphate dehydrogenase (NAD+) - mechanism: 1 - step: 2
m-csa:610 - precorrin-2 dehydrogenase - mechanism: 1 - step: 1
m-csa:619 - glyceraldehyde-3-phosphate dehydrogenase (NAD(P)+) (phosphorylating) - mechanism: 1 - step: 3
m-csa:687 - deoxyhypusine synthase - mechanism: 1 - step: 1
m-csa:711 - glyceraldehyde-3-phosphate dehydrogenase (NADP+) - mechanism: 1 - step: 2
m-csa:741 - histidinol dehydrogenase - mechanism: 1 - step: 1
m-csa:741 - histidinol dehydrogenase - mechanism: 1 - step: 3
m-csa:775 - shikimate dehydrogenase - mechanism: 1 - step: 1
m-csa:785 - phosphoglycerate dehydrogenase - mechanism: 1 - step: 1
m-csa:803 - aldehyde dehydrogenase (NAD+) (class 2) - mechanism: 1 - step: 3
m-csa:843 - glucose-6-phosphate dehydrogenase - mechanism: 1 - step: 1
m-csa:889 - phosphogluconate dehydrogenase (decarboxylating) - mechanism: 1 - step: 1
m-csa:984 - phosphonate dehydrogenase - mechanism: 1 - step: 2