All rules > rule id: 803194

Reaction SMARTS

[#1+0:1]-[#7+0:24]1-[#6+0:20]2=[#6+0:19](-[#7+0:21](-[#6+0:22])-[#6+0:23]=[#6+0:30]-1-[#6,#1;+0:32])-[#7-:27]-[#6+0:26](=[#8+0:28])-[#7+0:29]-[#6+0:25]-2=[#8+0:31].[#6+0:2]1(-[#6+0:3](-[#1,#6;+0:4])=[#6+0:5](-[#7+:10](=[#6+0:7](-[#6+0:6]=1-[#6+0:8](=[#8+0:11])-[#7+0:12])-[#1+0:13])-[#6+0:14](-[#8+0:15])(-[#6,#1;+0:16])-[#1,#6;+0:18])-[#1,#6;+0:17])-[#1+0:9]>>[#1+0:1]-[#6+0:2]1(-[#6+0:3](-[#1,#6;+0:4])=[#6+0:5](-[#7+0:10](-[#6+0:7](=[#6+0:6]-1-[#6+0:8](=[#8+0:11])-[#7+0:12])-[#1+0:13])-[#6+0:14](-[#8+0:15])(-[#6,#1;+0:16])-[#1,#6;+0:18])-[#1,#6;+0:17])-[#1+0:9].[#6+0:19]12-[#6+0:20](=[#7+0:24]-[#6+0:30](=[#6+0:23]-[#7+0:21]-1-[#6+0:22])-[#6,#1;+0:32])-[#6+0:25](-[#7+0:29]-[#6+0:26](-[#7+0:27]=2)=[#8+0:28])=[#8+0:31]

Simplified SMARTS

[H]N1C2=C(N(C)C=C1*)[N-]C(=O)NC2=O.C1([H])=C(C(=O)N)C([H])=[N+](C(O)(*)*)C(*)=C1*>>[H]C1([H])C(*)=C(*)N(C(O)(*)*)C([H])=C1C(=O)N.C12=NC(=O)NC(=O)C1=NC(*)=CN2C

Rule Set Version: 0.2
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Complete rule seen in 8 catalytic steps

m-csa:108 - 2,4-dienoyl-CoA reductase (NADPH) - mechanism: 1 - step: 1
m-csa:130 - naphthalene 1,2-dioxygenase - mechanism: 2 - step: 1
m-csa:131 - 4-hydroxybenzoate 3-monooxygenase - mechanism: 1 - step: 2
m-csa:277 - mercury(II) reductase - mechanism: 1 - step: 12
m-csa:277 - mercury(II) reductase - mechanism: 2 - step: 12
m-csa:304 - glutamate synthase (NADPH) - mechanism: 1 - step: 1
m-csa:551 - phenol 2-monooxygenase - mechanism: 1 - step: 1
m-csa:800 - dihydropyrimidine dehydrogenase (NADP+) - mechanism: 1 - step: 1

Rule partially seen in 58 catalytic steps

m-csa:6 - glutathione-disulfide reductase - mechanism: 1 - step: 1
m-csa:90 - adenosylhomocysteinase - mechanism: 1 - step: 5
m-csa:93 - hydroxymethylglutaryl-CoA reductase (NADPH) - mechanism: 2 - step: 1
m-csa:93 - hydroxymethylglutaryl-CoA reductase (NADPH) - mechanism: 1 - step: 3
m-csa:93 - hydroxymethylglutaryl-CoA reductase (NADPH) - mechanism: 1 - step: 1
m-csa:93 - hydroxymethylglutaryl-CoA reductase (NADPH) - mechanism: 3 - step: 3
m-csa:93 - hydroxymethylglutaryl-CoA reductase (NADPH) - mechanism: 3 - step: 1
m-csa:93 - hydroxymethylglutaryl-CoA reductase (NADPH) - mechanism: 2 - step: 3
m-csa:103 - vanillyl-alcohol oxidase - mechanism: 1 - step: 2
m-csa:110 - D-amino-acid oxidase - mechanism: 1 - step: 1
m-csa:110 - D-amino-acid oxidase - mechanism: 2 - step: 2
m-csa:113 - sarcosine oxidase - mechanism: 2 - step: 1
m-csa:115 - cytokinin dehydrogenase - mechanism: 1 - step: 1
m-csa:117 - NADPH-hemoprotein reductase - mechanism: 1 - step: 1
m-csa:120 - methylenetetrahydrofolate reductase [NAD(P)H] - mechanism: 1 - step: 1
m-csa:142 - ferredoxin-NADP+ reductase (adrenodoxin-type) - mechanism: 1 - step: 1
m-csa:188 - UDP-glucose 4-epimerase - mechanism: 2 - step: 2
m-csa:211 - oxygen insensitive NAD(P)H nitroreductase - mechanism: 1 - step: 4
m-csa:211 - oxygen insensitive NAD(P)H nitroreductase - mechanism: 1 - step: 1
m-csa:226 - UDP-sulfoquinovose synthase - mechanism: 1 - step: 4
m-csa:227 - GDP-L-fucose synthase - mechanism: 1 - step: 5
m-csa:228 - dTDP-glucose 4,6-dehydratase - mechanism: 2 - step: 4
m-csa:228 - dTDP-glucose 4,6-dehydratase - mechanism: 1 - step: 3
m-csa:237 - pteridine reductase - mechanism: 1 - step: 3
m-csa:264 - squalene synthase - mechanism: 1 - step: 7
m-csa:353 - UDP-N-acetylenolpyruvylglucosamine reductase (MurB) - mechanism: 1 - step: 1
m-csa:354 - cholesterol oxidase (GMC type) - mechanism: 1 - step: 1
m-csa:555 - L-amino-acid oxidase - mechanism: 1 - step: 2
m-csa:557 - ADP-glyceromanno-heptose 6-epimerase - mechanism: 2 - step: 2
m-csa:557 - ADP-glyceromanno-heptose 6-epimerase - mechanism: 1 - step: 2
m-csa:567 - glucose oxidase - mechanism: 1 - step: 1
m-csa:606 - enoyl-[acyl-carrier-protein] reductase (NADH) - mechanism: 1 - step: 1
m-csa:618 - saccharopine dehydrogenase (NADP+, L-glutamate-forming) - mechanism: 1 - step: 3
m-csa:620 - enoyl-[acyl-carrier-protein] reductase (NADPH, B-specific) - mechanism: 1 - step: 1
m-csa:627 - protein-disulfide reductase - mechanism: 1 - step: 4
m-csa:673 - cellobiose dehydrogenase (acceptor) - mechanism: 1 - step: 1
m-csa:687 - deoxyhypusine synthase - mechanism: 1 - step: 6
m-csa:721 - 2-dehydropantoate 2-reductase - mechanism: 1 - step: 1
m-csa:739 - L-aspartate oxidase - mechanism: 1 - step: 1
m-csa:739 - L-aspartate oxidase - mechanism: 2 - step: 1
m-csa:765 - 3-dehydro-L-gulonate 2-dehydrogenase - mechanism: 1 - step: 1
m-csa:804 - glutamyl-tRNA reductase - mechanism: 1 - step: 2
m-csa:822 - cholesterol oxidase - mechanism: 1 - step: 1
m-csa:891 - Tetrahydroxynaphthalene reductase - mechanism: 1 - step: 1
m-csa:925 - Nitrate reductase [NADH] - mechanism: 3 - step: 1
m-csa:942 - NikD - mechanism: 1 - step: 5
m-csa:942 - NikD - mechanism: 1 - step: 1
m-csa:967 - NADPH-dependent 7-cyano-7-deazaguanine reductase - mechanism: 1 - step: 7
m-csa:967 - NADPH-dependent 7-cyano-7-deazaguanine reductase - mechanism: 1 - step: 4
m-csa:969 - Phytoene desaturase (lycopene-forming) - mechanism: 2 - step: 5
m-csa:969 - Phytoene desaturase (lycopene-forming) - mechanism: 2 - step: 7
m-csa:969 - Phytoene desaturase (lycopene-forming) - mechanism: 2 - step: 3
m-csa:969 - Phytoene desaturase (lycopene-forming) - mechanism: 2 - step: 1
m-csa:974 - fatty acid synthase - β-ketoreductase (KR) - mechanism: 1 - step: 1
m-csa:977 - tryptophan 7-halogenase - mechanism: 1 - step: 1
m-csa:978 - D-arginine dehydrogenase - mechanism: 2 - step: 2
m-csa:978 - D-arginine dehydrogenase - mechanism: 1 - step: 2
m-csa:982 - GMP reductase - mechanism: 1 - step: 2