All rules > rule id: 800105

Reaction SMARTS

[#8+0:1]-[#6+0:2](-[#6,#1;+0:3])(-[#7+0:4]1-[#6+0:5](=[#6+0:10](-[#6+0:9](-[#6+0:8](=[#6+0:6]-1-[#1,#6;+0:7])-[#1,#6;+0:14])(-[#1+0:15])-[#1+0:18])-[#6+0:11](=[#8+0:16])-[#7+0:17])-[#1+0:12])-[#1,#6;+0:13].[#6+:19](-[#6+0:20](-[#8-:21])=[#8+0:22])(-[#6+0:23](-[#1,#6;+0:24])(-[#1,#6;+0:25])-[#1,#6;+0:26])-[#8+0:27]-[#1+0:28]>>[#8+0:1]-[#6+0:2](-[#6,#1;+0:3])(-[#7+:4]1=[#6+0:5](-[#6+0:10](=[#6+0:9](-[#6+0:8](=[#6+0:6]-1-[#1,#6;+0:7])-[#1,#6;+0:14])-[#1+0:15])-[#6+0:11](=[#8+0:16])-[#7+0:17])-[#1+0:12])-[#1,#6;+0:13].[#1+0:18]-[#6+0:19](-[#6+0:20](-[#8-:21])=[#8+0:22])(-[#6+0:23](-[#1,#6;+0:24])(-[#1,#6;+0:25])-[#1,#6;+0:26])-[#8+0:27]-[#1+0:28]

Simplified SMARTS

OC(*)(N1C([H])=C(C(=O)N)C([H])([H])C(*)=C1*)*.[C+](C([O-])=O)(C(*)(*)*)O[H]>>OC(*)([N+]1=C([H])C(C(=O)N)=C([H])C(*)=C1*)*.[H]C(C([O-])=O)(C(*)(*)*)O[H]

Rule Set Version: 0.2
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Complete rule seen in 2 catalytic steps

m-csa:576 - D-lactate dehydrogenase - mechanism: 1 - step: 1
m-csa:584 - L-lactate dehydrogenase - mechanism: 1 - step: 1

Rule partially seen in 41 catalytic steps

m-csa:7 - isocitrate dehydrogenase (NADP+) - mechanism: 1 - step: 1
m-csa:7 - isocitrate dehydrogenase (NADP+) - mechanism: 3 - step: 2
m-csa:7 - isocitrate dehydrogenase (NADP+) - mechanism: 2 - step: 1
m-csa:21 - malate dehydrogenase (oxaloacetate-decarboxylating) - mechanism: 1 - step: 1
m-csa:59 - 3-dehydroquinate synthase - mechanism: 1 - step: 1
m-csa:67 - alanine dehydrogenase - mechanism: 1 - step: 1
m-csa:90 - adenosylhomocysteinase - mechanism: 1 - step: 2
m-csa:92 - UDP-glucose 6-dehydrogenase - mechanism: 1 - step: 3
m-csa:92 - UDP-glucose 6-dehydrogenase - mechanism: 2 - step: 1
m-csa:92 - UDP-glucose 6-dehydrogenase - mechanism: 2 - step: 3
m-csa:92 - UDP-glucose 6-dehydrogenase - mechanism: 1 - step: 1
m-csa:100 - betaine-aldehyde dehydrogenase - mechanism: 1 - step: 2
m-csa:116 - NAD(P)+ transhydrogenase (AB-specific) - mechanism: 1 - step: 2
m-csa:188 - UDP-glucose 4-epimerase - mechanism: 2 - step: 1
m-csa:188 - UDP-glucose 4-epimerase - mechanism: 1 - step: 1
m-csa:226 - UDP-sulfoquinovose synthase - mechanism: 1 - step: 1
m-csa:228 - dTDP-glucose 4,6-dehydratase - mechanism: 2 - step: 1
m-csa:228 - dTDP-glucose 4,6-dehydratase - mechanism: 1 - step: 1
m-csa:255 - alcohol dehydrogenase (SDR type) - mechanism: 1 - step: 2
m-csa:256 - alcohol dehydrogenase (class I) - mechanism: 1 - step: 1
m-csa:312 - glycerol dehydrogenase - mechanism: 1 - step: 1
m-csa:331 - inositol-3-phosphate synthase - mechanism: 1 - step: 1
m-csa:336 - L-3-hydroxyacyl-CoA dehydrogenase - mechanism: 1 - step: 2
m-csa:526 - malate dehydrogenase (type 2) - mechanism: 1 - step: 1
m-csa:527 - malate dehydrogenase (type 1) - mechanism: 1 - step: 1
m-csa:557 - ADP-glyceromanno-heptose 6-epimerase - mechanism: 2 - step: 1
m-csa:557 - ADP-glyceromanno-heptose 6-epimerase - mechanism: 1 - step: 1
m-csa:579 - glutamate dehydrogenase - mechanism: 1 - step: 1
m-csa:593 - glycerol-3-phosphate dehydrogenase (NAD+) - mechanism: 1 - step: 2
m-csa:610 - precorrin-2 dehydrogenase - mechanism: 1 - step: 1
m-csa:619 - glyceraldehyde-3-phosphate dehydrogenase (NAD(P)+) (phosphorylating) - mechanism: 1 - step: 3
m-csa:687 - deoxyhypusine synthase - mechanism: 1 - step: 1
m-csa:711 - glyceraldehyde-3-phosphate dehydrogenase (NADP+) - mechanism: 1 - step: 2
m-csa:741 - histidinol dehydrogenase - mechanism: 1 - step: 3
m-csa:741 - histidinol dehydrogenase - mechanism: 1 - step: 1
m-csa:775 - shikimate dehydrogenase - mechanism: 1 - step: 1
m-csa:785 - phosphoglycerate dehydrogenase - mechanism: 1 - step: 1
m-csa:803 - aldehyde dehydrogenase (NAD+) (class 2) - mechanism: 1 - step: 3
m-csa:843 - glucose-6-phosphate dehydrogenase - mechanism: 1 - step: 1
m-csa:889 - phosphogluconate dehydrogenase (decarboxylating) - mechanism: 1 - step: 1
m-csa:984 - phosphonate dehydrogenase - mechanism: 1 - step: 2