8-demethyl-8-(2,3-O-dimethyl-alpha-L-rhamnosyl)tetracenomycin C (CHEBI:78286)

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CHEBI:78286 - 8-demethyl-8-(2,3-O-dimethyl-α-L-rhamnosyl)tetracenomycin C

ChEBI ID	CHEBI:78286
ChEBI Name	8-demethyl-8-(2,3-O-dimethyl-α-L-rhamnosyl)tetracenomycin C
Stars
ASCII Name	8-demethyl-8-(2,3-O-dimethyl-alpha-L-rhamnosyl)tetracenomycin C
Definition	A member of the class of tetracenomycins that is 8-demethyltetracenomycin C in which the hydroxyl hydrogen at position 8 is replaced by a 2,3-di-O-methyl-α-L-rhamnosyl residue.
Last Modified	6 February 2018
Submitter	KAX
Downloads	Molfile

Formula	C30H32O15
Net Charge	0
Average Mass	632.571
Monoisotopic Mass	632.17412
SMILES	COC(=O)c1c(O[C@@H]2O[C@@H](C)[C@H](O)[C@@H](OC)[C@H]2OC)cc2cc3c(c(O)c2c1C)C(=O)[C@]1(O)C(=O)C=C(OC)[C@@H](O)[C@]1(O)C3=O
InChI	InChI=1S/C30H32O15/c1-10-17-12(8-14(18(10)27(37)43-6)45-28-23(42-5)22(41-4)20(32)11(2)44-28)7-13-19(21(17)33)26(36)29(38)16(31)9-15(40-3)25(35)30(29,39)24(13)34/h7-9,11,20,22-23,25,28,32-33,35,38-39H,1-6H3/t11-,20-,22+,23+,25+,28-,29+,30+/m0/s1
InChIKey	NIRLIWMQNRJEDG-RARRKIFNSA-N

Species of Metabolite	Component	Source	Comments
Streptomyces olivaceus (ncbitaxon:47716)	-	PubMed (11376004)

Roles Classification

Biological Roles:

bacterial metabolite Any prokaryotic metabolite produced during a metabolic reaction in bacteria.

metabolite Any intermediate or product resulting from metabolism. The term 'metabolite' subsumes the classes commonly known as primary and secondary metabolites.

antimicrobial agent A substance that kills or slows the growth of microorganisms, including bacteria, viruses, fungi and protozoans.

ChEBI Ontology

Outgoing Relation(s)
	8-demethyl-8-(2,3-O-dimethyl-α-L-rhamnosyl)tetracenomycin C (CHEBI:78286) has functional parent tetracenomycin C (CHEBI:9470)
	8-demethyl-8-(2,3-O-dimethyl-α-L-rhamnosyl)tetracenomycin C (CHEBI:78286) has role bacterial metabolite (CHEBI:76969)
	8-demethyl-8-(2,3-O-dimethyl-α-L-rhamnosyl)tetracenomycin C (CHEBI:78286) is a enol ether (CHEBI:47985)
	8-demethyl-8-(2,3-O-dimethyl-α-L-rhamnosyl)tetracenomycin C (CHEBI:78286) is a enone (CHEBI:51689)
	8-demethyl-8-(2,3-O-dimethyl-α-L-rhamnosyl)tetracenomycin C (CHEBI:78286) is a methyl ester (CHEBI:25248)
	8-demethyl-8-(2,3-O-dimethyl-α-L-rhamnosyl)tetracenomycin C (CHEBI:78286) is a monosaccharide derivative (CHEBI:63367)
	8-demethyl-8-(2,3-O-dimethyl-α-L-rhamnosyl)tetracenomycin C (CHEBI:78286) is a phenols (CHEBI:33853)
	8-demethyl-8-(2,3-O-dimethyl-α-L-rhamnosyl)tetracenomycin C (CHEBI:78286) is a tertiary α-hydroxy ketone (CHEBI:139592)
	8-demethyl-8-(2,3-O-dimethyl-α-L-rhamnosyl)tetracenomycin C (CHEBI:78286) is a tetracenequinones (CHEBI:51286)
	8-demethyl-8-(2,3-O-dimethyl-α-L-rhamnosyl)tetracenomycin C (CHEBI:78286) is a tetracenomycin (CHEBI:48132)
	8-demethyl-8-(2,3-O-dimethyl-α-L-rhamnosyl)tetracenomycin C (CHEBI:78286) is a α-L-rhamnoside (CHEBI:27848)

IUPAC Name
methyl (6aR,7S,10aR)-3-[(6-deoxy-2,3-di-O-methyl-α-L-mannopyranosyl)oxy]-6a,7,10a,12-tetrahydroxy-8-methoxy-1-methyl-6,10,11-trioxo-6,6a,7,10,10a,11-hexahydrotetracene-2-carboxylate

UniProt Name	Source
8-demethyl-8-(2,3-di-O-methyl-α-L-rhamnosyl)-tetracenomycin C	UniProt

Manual Xrefs	Databases
CPD-16639	MetaCyc

Citations