8-demethyl-8-(2-O-methyl-alpha-L-rhamnosyl)tetracenomycin C (CHEBI:78285)

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CHEBI:78285 - 8-demethyl-8-(2-O-methyl-α-L-rhamnosyl)tetracenomycin C

ChEBI ID	CHEBI:78285
ChEBI Name	8-demethyl-8-(2-O-methyl-α-L-rhamnosyl)tetracenomycin C
Stars
ASCII Name	8-demethyl-8-(2-O-methyl-alpha-L-rhamnosyl)tetracenomycin C
Definition	A member of the class of tetracenomycins that is 8-demethyltetracenomycin C in which the hydroxyl hydrogen at position 8 is replaced by a 2-O-methyl-α-L-rhamnosyl residue.
Last Modified	6 February 2018
Submitter	KAX
Downloads	Molfile

Formula	C29H30O15
Net Charge	0
Average Mass	618.544
Monoisotopic Mass	618.15847
SMILES	COC(=O)c1c(O[C@@H]2O[C@@H](C)[C@H](O)[C@@H](O)[C@H]2OC)cc2cc3c(c(O)c2c1C)C(=O)[C@]1(O)C(=O)C=C(OC)[C@@H](O)[C@]1(O)C3=O
InChI	InChI=1S/C29H30O15/c1-9-16-11(7-13(17(9)26(37)42-5)44-27-22(41-4)21(33)19(31)10(2)43-27)6-12-18(20(16)32)25(36)28(38)15(30)8-14(40-3)24(35)29(28,39)23(12)34/h6-8,10,19,21-22,24,27,31-33,35,38-39H,1-5H3/t10-,19-,21+,22+,24+,27-,28+,29+/m0/s1
InChIKey	HDQAHAYFRSTUFM-LMEYJBJCSA-N

Species of Metabolite	Component	Source	Comments
Streptomyces olivaceus (ncbitaxon:47716)	-	PubMed (11376004)

Roles Classification

Biological Roles:

bacterial metabolite Any prokaryotic metabolite produced during a metabolic reaction in bacteria.

antimicrobial agent A substance that kills or slows the growth of microorganisms, including bacteria, viruses, fungi and protozoans.

metabolite Any intermediate or product resulting from metabolism. The term 'metabolite' subsumes the classes commonly known as primary and secondary metabolites.

ChEBI Ontology

Outgoing Relation(s)
	8-demethyl-8-(2-O-methyl-α-L-rhamnosyl)tetracenomycin C (CHEBI:78285) has functional parent tetracenomycin C (CHEBI:9470)
	8-demethyl-8-(2-O-methyl-α-L-rhamnosyl)tetracenomycin C (CHEBI:78285) has role bacterial metabolite (CHEBI:76969)
	8-demethyl-8-(2-O-methyl-α-L-rhamnosyl)tetracenomycin C (CHEBI:78285) is a enol ether (CHEBI:47985)
	8-demethyl-8-(2-O-methyl-α-L-rhamnosyl)tetracenomycin C (CHEBI:78285) is a enone (CHEBI:51689)
	8-demethyl-8-(2-O-methyl-α-L-rhamnosyl)tetracenomycin C (CHEBI:78285) is a methyl ester (CHEBI:25248)
	8-demethyl-8-(2-O-methyl-α-L-rhamnosyl)tetracenomycin C (CHEBI:78285) is a monosaccharide derivative (CHEBI:63367)
	8-demethyl-8-(2-O-methyl-α-L-rhamnosyl)tetracenomycin C (CHEBI:78285) is a phenols (CHEBI:33853)
	8-demethyl-8-(2-O-methyl-α-L-rhamnosyl)tetracenomycin C (CHEBI:78285) is a tertiary α-hydroxy ketone (CHEBI:139592)
	8-demethyl-8-(2-O-methyl-α-L-rhamnosyl)tetracenomycin C (CHEBI:78285) is a tetracenequinones (CHEBI:51286)
	8-demethyl-8-(2-O-methyl-α-L-rhamnosyl)tetracenomycin C (CHEBI:78285) is a tetracenomycin (CHEBI:48132)
	8-demethyl-8-(2-O-methyl-α-L-rhamnosyl)tetracenomycin C (CHEBI:78285) is a α-L-rhamnoside (CHEBI:27848)

IUPAC Name
methyl (6aR,7S,10aR)-3-[(6-deoxy-2-O-methyl-α-L-mannopyranosyl)oxy]-6a,7,10a,12-tetrahydroxy-8-methoxy-1-methyl-6,10,11-trioxo-6,6a,7,10,10a,11-hexahydrotetracene-2-carboxylate

Synonym	Source
8-demethyl-8-(2-methoxy-α-L-rhamnosyl)tetracenomycin C	SUBMITTER

UniProt Name	Source
8-demethyl-8-(2-O-methyl-α-L-rhamnosyl)-tetracenomycin C	UniProt

Manual Xrefs	Databases
CPD-16640	MetaCyc

Citations