8-demethyl-8-(alpha-L-rhamnosyl)tetracenomycin C (CHEBI:78283)

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CHEBI:78283 - 8-demethyl-8-(α-L-rhamnosyl)tetracenomycin C

ChEBI ID	CHEBI:78283
ChEBI Name	8-demethyl-8-(α-L-rhamnosyl)tetracenomycin C
Stars
ASCII Name	8-demethyl-8-(alpha-L-rhamnosyl)tetracenomycin C
Definition	A member of the class of tetracenomycins that is 8-demethyltetracenomycin C in which the hydroxyl hydrogen at position 8 is replaced by an α-L-rhamnosyl residue.
Last Modified	6 February 2018
Submitter	KAX
Downloads	Molfile

Formula	C28H28O15
Net Charge	0
Average Mass	604.517
Monoisotopic Mass	604.14282
SMILES	COC(=O)c1c(O[C@@H]2O[C@@H](C)[C@H](O)[C@@H](O)[C@H]2O)cc2cc3c(c(O)c2c1C)C(=O)[C@]1(O)C(=O)C=C(OC)[C@@H](O)[C@]1(O)C3=O
InChI	InChI=1S/C28H28O15/c1-8-15-10(6-12(16(8)25(37)41-4)43-26-21(33)20(32)18(30)9(2)42-26)5-11-17(19(15)31)24(36)27(38)14(29)7-13(40-3)23(35)28(27,39)22(11)34/h5-7,9,18,20-21,23,26,30-33,35,38-39H,1-4H3/t9-,18-,20+,21+,23+,26-,27+,28+/m0/s1
InChIKey	QIJXKOOPLDVFLW-DWENXZEQSA-N

Species of Metabolite	Component	Source	Comments
Streptomyces olivaceus (ncbitaxon:47716)	-	PubMed (11376004)

Roles Classification

Biological Roles:

bacterial metabolite Any prokaryotic metabolite produced during a metabolic reaction in bacteria.

antimicrobial agent A substance that kills or slows the growth of microorganisms, including bacteria, viruses, fungi and protozoans.

metabolite Any intermediate or product resulting from metabolism. The term 'metabolite' subsumes the classes commonly known as primary and secondary metabolites.

ChEBI Ontology

Outgoing Relation(s)
	8-demethyl-8-(α-L-rhamnosyl)tetracenomycin C (CHEBI:78283) has functional parent tetracenomycin C (CHEBI:9470)
	8-demethyl-8-(α-L-rhamnosyl)tetracenomycin C (CHEBI:78283) has role bacterial metabolite (CHEBI:76969)
	8-demethyl-8-(α-L-rhamnosyl)tetracenomycin C (CHEBI:78283) is a cyclic ketone (CHEBI:3992)
	8-demethyl-8-(α-L-rhamnosyl)tetracenomycin C (CHEBI:78283) is a enol ether (CHEBI:47985)
	8-demethyl-8-(α-L-rhamnosyl)tetracenomycin C (CHEBI:78283) is a enone (CHEBI:51689)
	8-demethyl-8-(α-L-rhamnosyl)tetracenomycin C (CHEBI:78283) is a methyl ester (CHEBI:25248)
	8-demethyl-8-(α-L-rhamnosyl)tetracenomycin C (CHEBI:78283) is a monosaccharide derivative (CHEBI:63367)
	8-demethyl-8-(α-L-rhamnosyl)tetracenomycin C (CHEBI:78283) is a phenols (CHEBI:33853)
	8-demethyl-8-(α-L-rhamnosyl)tetracenomycin C (CHEBI:78283) is a tertiary α-hydroxy ketone (CHEBI:139592)
	8-demethyl-8-(α-L-rhamnosyl)tetracenomycin C (CHEBI:78283) is a tetracenomycin (CHEBI:48132)
	8-demethyl-8-(α-L-rhamnosyl)tetracenomycin C (CHEBI:78283) is a α-L-rhamnoside (CHEBI:27848)

IUPAC Name
methyl (6aR,7S,10aR)-3-[(6-deoxy-α-L-mannopyranosyl)oxy]-6a,7,10a,12-tetrahydroxy-8-methoxy-1-methyl-6,10,11-trioxo-6,6a,7,10,10a,11-hexahydrotetracene-2-carboxylate

UniProt Name	Source
8-demethyl-8-α-L-rhamnosyl-tetracenomycin C	UniProt

Manual Xrefs	Databases
CPD-16641	MetaCyc

Citations