elaiophylin (CHEBI:77879)

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CHEBI:77879 - elaiophylin

ChEBI ID	CHEBI:77879
ChEBI Name	elaiophylin
Stars
Definition	A macrodiolide that is isolated from several bacteria including Streptomyces violaceoniger and other soil actinomycetes.
Last Modified	2 December 2019
Submitter	Steve
Downloads	Molfile

Formula	C54H88O18
Net Charge	0
Average Mass	1025.280
Monoisotopic Mass	1024.59707
SMILES	[H][C@]1([C@@H](C)[C@@H](O)[C@H](C)[C@@]2(O)C[C@@H](O[C@H]3C[C@H](O)[C@H](O)[C@H](C)O3)[C@H](CC)[C@@H](C)O2)OC(=O)/C=C/C=C/[C@H](C)[C@@]([H])([C@@H](C)[C@@H](O)[C@H](C)[C@@]2(O)C[C@@H](O[C@H]3C[C@H](O)[C@H](O)[C@H](C)O3)[C@H](CC)[C@@H](C)O2)OC(=O)/C=C/C=C/[C@@H]1C
InChI	InChI=1S/C54H88O18/c1-13-37-33(9)71-53(63,25-41(37)67-45-23-39(55)49(61)35(11)65-45)31(7)47(59)29(5)51-27(3)19-15-17-22-44(58)70-52(28(4)20-16-18-21-43(57)69-51)30(6)48(60)32(8)54(64)26-42(38(14-2)34(10)72-54)68-46-24-40(56)50(62)36(12)66-46/h15-22,27-42,45-52,55-56,59-64H,13-14,23-26H2,1-12H3/b19-15+,20-16+,21-18+,22-17+/t27-,28-,29-,30-,31-,32-,33+,34+,35-,36-,37+,38+,39-,40-,41+,42+,45-,46-,47+,48+,49+,50+,51-,52-,53+,54+/m0/s1
InChIKey	OSERMIPXNLXAPD-MJMYBOKFSA-N

Roles Classification

Biological Roles:

bacterial metabolite Any prokaryotic metabolite produced during a metabolic reaction in bacteria.

antifungal agent An antimicrobial agent that destroys fungi by suppressing their ability to grow or reproduce.

autophagy inhibitor Any compound that inhibits the process of autophagy (the self-digestion of one or more components of a cell through the action of enzymes originating within the same cell).

ChEBI Ontology

Outgoing Relation(s)
	elaiophylin (CHEBI:77879) has role antifungal agent (CHEBI:35718)
	elaiophylin (CHEBI:77879) has role autophagy inhibitor (CHEBI:88230)
	elaiophylin (CHEBI:77879) has role bacterial metabolite (CHEBI:76969)
	elaiophylin (CHEBI:77879) is a lactol (CHEBI:38131)
	elaiophylin (CHEBI:77879) is a macrodiolide (CHEBI:145556)
	elaiophylin (CHEBI:77879) is a monosaccharide derivative (CHEBI:63367)

IUPAC Name
(3E,5E,7S,8S,11E,13E,15S,16S)-8,16-bis{(2S,3R,4S)-4-[(2R,4R,5R,6R)-4-{[(2R,4S,5S,6S)-4,5-dihydroxy-6-methyltetrahydro-2H-pyran-2-yl]oxy}-5-ethyl-2-hydroxy-6-methyltetrahydro-2H-pyran-2-yl]-3-hydroxypentan-2-yl}-7,15-dimethyl-1,9-dioxacyclohexadeca-3,5,11,13-tetraene-2,10-dione

Synonyms	Source
Antibiotic 5001B	ChemIDplus
Antibiotic 56-62	ChemIDplus
Azalomycin B	ChemIDplus
gopalamicin	ChEBI
salbomycin	ChEBI

Manual Xrefs	Databases
C15844	KEGG COMPOUND

Registry Numbers	Sources
Reaxys:4227388	Reaxys
CAS:37318-06-2	ChemIDplus

Citations