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CHEBI:69378 - hermannioside B

ChEBI IDCHEBI:69378
ChEBI Namehermannioside B
Stars
DefinitionA glycosyloxyflavone that is kaempferol attached to α-L-rhamnopyranosyl-(1→2)-α-L-arabinopyranosyl residue at position 3 and a α-L-rhamnopyranosyl residue at position 7 via glycosidic linkages. It has been isolated from the whole plant of Anthyllis hermanniae.
Last Modified27 November 2013
DownloadsMolfile
FormulaC32H38O18
Net Charge0
Average Mass710.638
Monoisotopic Mass710.20581
SMILES[H][C@@]1(O[C@H]2[C@H](Oc3c(-c4ccc(O)cc4)oc4cc(O[C@@H]5O[C@@H](C)[C@H](O)[C@@H](O)[C@H]5O)cc(O)c4c3=O)OC[C@H](O)[C@@H]2O)O[C@@H](C)[C@H](O)[C@@H](O)[C@H]1O
InChIInChI=1S/C32H38O18/c1-10-19(36)23(40)25(42)30(45-10)47-14-7-15(34)18-17(8-14)48-27(12-3-5-13(33)6-4-12)28(22(18)39)49-32-29(21(38)16(35)9-44-32)50-31-26(43)24(41)20(37)11(2)46-31/h3-8,10-11,16,19-21,23-26,29-38,40-43H,9H2,1-2H3/t10-,11-,16-,19-,20-,21-,23+,24+,25+,26+,29+,30-,31-,32-/m0/s1
InChIKeyWNEKTAXRNDLFBT-UOFFBVERSA-N
Species of MetaboliteComponentSourceComments
Anthyllis hermanniae (ncbitaxon:181246) whole plant (BTO:0001461) PubMed (21861458) Methanolic extract of air dried and powdered plant
Roles Classification
Biological Roles:
metabolite  Any intermediate or product resulting from metabolism. The term 'metabolite' subsumes the classes commonly known as primary and secondary metabolites.
plant metabolite  Any eukaryotic metabolite produced during a metabolic reaction in plants, the kingdom that include flowering plants, conifers and other gymnosperms.
ChEBI Ontology
Outgoing Relation(s)
hermannioside B (CHEBI:69378) has functional parent kaempferol (CHEBI:28499)
hermannioside B (CHEBI:69378) has role metabolite (CHEBI:25212)
hermannioside B (CHEBI:69378) has role plant metabolite (CHEBI:76924)
hermannioside B (CHEBI:69378) is a dihydroxyflavone (CHEBI:38686)
hermannioside B (CHEBI:69378) is a glycosyloxyflavone (CHEBI:50018)
hermannioside B (CHEBI:69378) is a α-L-arabinopyranoside (CHEBI:37782)
hermannioside B (CHEBI:69378) is a α-L-rhamnoside (CHEBI:27848)
IUPAC Name 
3-{[2-O-(6-deoxy-α-L-mannopyranosyl)-α-L-arabinopyranosyl]oxy}-5-hydroxy-2-(4-hydroxyphenyl)-4-oxo-4H-chromen-7-yl 6-deoxy-α-L-mannopyranoside
Synonym  Source
kaempferol 3-O-[α-L-rhamnopyranosyl-(1→2)-α-L-arabinopyranoside]-7-O-α-L-rhamnopyranosideChEBI
Registry NumbersSources
Reaxys:21897854Reaxys
Citations