[3)alpha-L-Rhap-(1->2)-alpha-D-Galp-(1->3)-alpha-D-GlcpNAc-(1->3)-alpha-L-Rhap(1->]4 (CHEBI:60478)

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CHEBI:60478 - [3)α-L-Rhap-(1→2)-α-D-Galp-(1→3)-α-D-GlcpNAc-(1→3)-α-L-Rhap(1→]₄

ChEBI ID	CHEBI:60478
ChEBI Name	[3)α-L-Rhap-(1→2)-α-D-Galp-(1→3)-α-D-GlcpNAc-(1→3)-α-L-Rhap(1→]₄
Stars
ASCII Name	[3)alpha-L-Rhap-(1->2)-alpha-D-Galp-(1->3)-alpha-D-GlcpNAc-(1->3)-alpha-L-Rhap(1->]4
Definition	The amino hexadecasaccharide obtained when four molecules of the repeating tetrasacchride unit from Shigella dysenteriae O-specific polysaccharide are joined via α-(1→3) linkages.
Last Modified	21 October 2010
Submitter	Steve
Downloads	Molfile

Formula	C104H174N4O73
Net Charge	0
Average Mass	2648.491
Monoisotopic Mass	2647.00262
SMILES	CC(=O)N[C@H]1[C@@H](O[C@@H]2[C@@H](O)[C@H](C)O[C@@H](O[C@@H]3[C@@H](O)[C@H](C)O[C@@H](O[C@H]4[C@@H](O[C@H]5[C@H](O)[C@@H](CO)O[C@H](O[C@@H]6[C@@H](O)[C@H](C)O[C@@H](O[C@@H]7[C@@H](O)[C@H](C)O[C@@H](O[C@H]8[C@@H](O[C@H]9[C@H](O)[C@@H](CO)O[C@H](O[C@@H]%10[C@@H](O)[C@H](C)O[C@@H](O[C@@H]%11[C@@H](O)[C@H](C)O[C@@H](O[C@H]%12[C@@H](O[C@H]%13[C@H](O)[C@@H](CO)O[C@H](O[C@@H]%14[C@@H](O)[C@H](C)O[C@@H](O)[C@@H]%14O)[C@@H]%13NC(C)=O)O[C@H](CO)[C@H](O)[C@@H]%12O)[C@@H]%11O)[C@@H]%10O)[C@@H]9NC(C)=O)O[C@H](CO)[C@H](O)[C@@H]8O)[C@@H]7O)[C@@H]6O)[C@@H]5NC(C)=O)O[C@H](CO)[C@H](O)[C@@H]4O)[C@@H]3O)[C@@H]2O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1O[C@H](CO)[C@H](O)[C@H](O)[C@H]1O[C@@H]1O[C@@H](C)[C@H](O)[C@@H](O)[C@H]1O
InChI	InChI=1S/C104H174N4O73/c1-21-45(121)61(137)66(142)94(152-21)178-85-62(138)53(129)33(13-109)163-101(85)167-75-42(106-30(10)118)91(160-38(18-114)58(75)134)172-79-47(123)23(3)153-95(68(79)144)176-83-51(127)27(7)157-99(72(83)148)180-87-64(140)55(131)35(15-111)165-103(87)169-77-44(108-32(12)120)93(162-40(20-116)60(77)136)174-81-49(125)25(5)155-97(70(81)146)177-84-52(128)28(8)158-100(73(84)149)181-88-65(141)56(132)36(16-112)166-104(88)170-76-43(107-31(11)119)92(161-39(19-115)59(76)135)173-80-48(124)24(4)154-96(69(80)145)175-82-50(126)26(6)156-98(71(82)147)179-86-63(139)54(130)34(14-110)164-102(86)168-74-41(105-29(9)117)90(159-37(17-113)57(74)133)171-78-46(122)22(2)151-89(150)67(78)143/h21-28,33-104,109-116,121-150H,13-20H2,1-12H3,(H,105,117)(H,106,118)(H,107,119)(H,108,120)/t21-,22-,23-,24-,25-,26-,27-,28-,33+,34+,35+,36+,37+,38+,39+,40+,41+,42+,43+,44+,45-,46-,47-,48-,49-,50-,51-,52-,53-,54-,55-,56-,57+,58+,59+,60+,61+,62-,63-,64-,65-,66+,67+,68+,69+,70+,71+,72+,73+,74+,75+,76+,77+,78+,79+,80+,81+,82+,83+,84+,85+,86+,87+,88+,89+,90+,91+,92+,93+,94-,95-,96-,97-,98-,99-,100-,101+,102+,103+,104+/m0/s1
InChIKey	NFCGYJOVDUGKGV-LHDHTXAMSA-N

Roles Classification

Biological Role:

hapten Any substance capable of eliciting an immune response only when attached to a large carrier such as a protein. Examples include dinitrophenols; oligosaccharides; peptides; and heavy metals.

ChEBI Ontology

Outgoing Relation(s)
	[3)α-L-Rhap-(1→2)-α-D-Galp-(1→3)-α-D-GlcpNAc-(1→3)-α-L-Rhap(1→]₄ (CHEBI:60478) has role hapten (CHEBI:59174)
	[3)α-L-Rhap-(1→2)-α-D-Galp-(1→3)-α-D-GlcpNAc-(1→3)-α-L-Rhap(1→]₄ (CHEBI:60478) is a amino oligosaccharide (CHEBI:22483)

IUPAC Name
α-L-rhamnopyranosyl-(1→2)-α-D-galactopyranosyl-(1→3)-2-acetamido-2-deoxy-α-D-glucopyranosyl-(1→3)-α-L-rhamnopyranosyl-(1→3)-α-L-rhamnopyranosyl-(1→2)-α-D-galactopyranosyl-(1→3)-2-acetamido-2-deoxy-α-D-glucopyranosyl-(1→3)-α-L-rhamnopyranosyl-(1→3)-α-L-rhamnopyranosyl-(1→2)-α-D-galactopyranosyl-(1→3)-2-acetamido-2-deoxy-α-D-glucopyranosyl-(1→3)-α-L-rhamnopyranosyl-(1→3)-α-L-rhamnopyranosyl-(1→2)-α-D-galactopyranosyl-(1→3)-2-acetamido-2-deoxy-α-D-glucopyranosyl-(1→3)-α-L-rhamnopyranose

IUPAC Name

α-L-rhamnopyranosyl-(1→2)-α-D-galactopyranosyl-(1→3)-2-acetamido-2-deoxy-α-D-glucopyranosyl-(1→3)-α-L-rhamnopyranosyl-(1→3)-α-L-rhamnopyranosyl-(1→2)-α-D-galactopyranosyl-(1→3)-2-acetamido-2-deoxy-α-D-glucopyranosyl-(1→3)-α-L-rhamnopyranosyl-(1→3)-α-L-rhamnopyranosyl-(1→2)-α-D-galactopyranosyl-(1→3)-2-acetamido-2-deoxy-α-D-glucopyranosyl-(1→3)-α-L-rhamnopyranosyl-(1→3)-α-L-rhamnopyranosyl-(1→2)-α-D-galactopyranosyl-(1→3)-2-acetamido-2-deoxy-α-D-glucopyranosyl-(1→3)-α-L-rhamnopyranose

Synonyms	Source
[3)α-L-Rha-(1→2)-α-D-Gal-(1→3)-α-D-GlcNAc-(1→3)-α-L-Rha(1→]₄	ChEBI
6-deoxy-α-L-mannopyranosyl-(1→2)-α-D-galactopyranosyl-(1→3)-2-acetamido-2-deoxy-α-D-glucopyranosyl-(1→3)-6-deoxy-α-L-mannopyranosyl-(1→3)-6-deoxy-α-L-mannopyranosyl-(1→2)-α-D-galactopyranosyl-(1→3)-2-acetamido-2-deoxy-α-D-glucopyranosyl-(1→3)-6-deoxy-α-L-mannopyranosyl-(1→3)-6-deoxy-α-L-mannopyranosyl-(1→2)-α-D-galactopyranosyl-(1→3)-2-acetamido-2-deoxy-α-D-glucopyranosyl-(1→3)-6-deoxy-α-L-mannopyranosyl-(1→3)-6-deoxy-α-L-mannopyranosyl-(1→2)-α-D-galactopyranosyl-(1→3)-2-acetamido-2-deoxy-α-D-glucopyranosyl-(1→3)-6-deoxy-α-L-mannopyranose	IUPAC

Synonyms

Source

[3)α-L-Rha-(1→2)-α-D-Gal-(1→3)-α-D-GlcNAc-(1→3)-α-L-Rha(1→]₄

ChEBI

6-deoxy-α-L-mannopyranosyl-(1→2)-α-D-galactopyranosyl-(1→3)-2-acetamido-2-deoxy-α-D-glucopyranosyl-(1→3)-6-deoxy-α-L-mannopyranosyl-(1→3)-6-deoxy-α-L-mannopyranosyl-(1→2)-α-D-galactopyranosyl-(1→3)-2-acetamido-2-deoxy-α-D-glucopyranosyl-(1→3)-6-deoxy-α-L-mannopyranosyl-(1→3)-6-deoxy-α-L-mannopyranosyl-(1→2)-α-D-galactopyranosyl-(1→3)-2-acetamido-2-deoxy-α-D-glucopyranosyl-(1→3)-6-deoxy-α-L-mannopyranosyl-(1→3)-6-deoxy-α-L-mannopyranosyl-(1→2)-α-D-galactopyranosyl-(1→3)-2-acetamido-2-deoxy-α-D-glucopyranosyl-(1→3)-6-deoxy-α-L-mannopyranose

IUPAC

Citations

CHEBI:60478 - [3)α-L-Rhap-(1→2)-α-D-Galp-(1→3)-α-D-GlcpNAc-(1→3)-α-L-Rhap(1→]4

CHEBI:60478 - [3)α-L-Rhap-(1→2)-α-D-Galp-(1→3)-α-D-GlcpNAc-(1→3)-α-L-Rhap(1→]₄