_EC 2.3.1.324 chlorogenate caffeoyltransferase. 0 PDB entries  
EC 2.-.-.- Transferases. [47,784 PDB entries]
EC 2.3.-.- Acyltransferases. [6,129 PDB entries]
EC 2.3.1.- Transferring groups other than amino-acyl groups. [3,260 PDB entries]
EC 2.3.1.324 chlorogenate caffeoyltransferase. [-]

Reaction: 2 chlorogenate = 3,5-di-O-caffeoyl quinate + L-quinate.
 


2 × chlorogenate
= 3,5-di-O-caffeoyl quinate
+
L-quinate
Molecule diagrams generated from .mol files obtained from the KEGG ftp site.

Comments: The enzyme has been purified from Solanum lycopersicum (tomato) fruits. In the vacuole, at pH 4-5, it produces 3,5-dicaffeoylquinic acid from cholorgenic acid. In the cytoplasm, at pH 6-7, it can use aromatic acyl-CoAs as donors and catalyzes the reaction of Ec 2.3.1.99. The initial product, 3,5-dicaffeoylquinic acid, undergoes spontaneous acyl migration to form 4,5-dicaffeoylquinic acid. Small amounts of 1,5-dicaffeoylquinic acid are formed as a by-product.
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There are no PDB entries in enzyme class E.C.2.3.1.324