|
Figure 8.
Fig. 8. Schematic reaction mechanism of myrosinase in the
absence (a) and presence (b and c) of ascorbic acid. E, enzyme;
S, substrate; GE, glucosyl enzyme; A, ascorbate; k[1], k[2],
etc., dissociation constants not involving ascorbate; k[3'],
rate constant in presence of ascorbate; k[A1], k[A 1],
etc., dissociation constants of ascorbate. The less important
back reactions are not shown.
|