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Figure 5.
Figure 5. The Chemical Kinetic Mechanism of E46Q PYP in the
Crystal
(A) Chemical kinetic mechanism of E46Q PYP in the
crystal, with rate coefficients (s -1) of 3.0 × 10^6 (IE1->IE2),
5.0 × 10^5 (IE2->IL1), 5.0 × 10^3 (IL1->IL2), 3.0 × 10^3
(IL1->G), 50 (IL2->IL3), and 0 (IL3->G).
(B) Predicted
concentrations of IE1 (red), IE2 (magenta), IL1 (blue), IL2
(cyan), IL3 (dashed), and the ground state (black) with the
mechanism in (A).
(C) Predicted concentration profiles for
spectroscopic intermediates pR (IE1 and IE2) shown in red, pB
(IL1 and IL2) shown in blue, and the ground state (IL3 and pG)
shown in black with the mechanism in (A).
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