|
Figure 4.
Figure 4: Spectra and refined high-resolution structures for the
five oxidation states of horseradish peroxidase. Accession
codes are shown. The structures were captured at high
concentrations in individual experiments (Methods) and were
obtained from the first few degrees of data (Table 2 of the
Supplementary Information). a, Ferric enzyme. b, Ferrous enzyme.
c, Compound III (Fe -O bond distance, 1.8 Å). d, Compound I (Fe
-O bond distance, 1.7 Å). e, Compound II (Fe -O bond distance,
1.8 Å). SigmaA-weighted^30 2mF[obs] -DF[calc] maps contoured at
1 .
|