_EC 4.2.3.97 (-)-delta-cadinene synthase.

0 PDB entries

EC 4.-.-.- Lyases. [10,261 PDB entries] EC 4.2.-.- Carbon-oxygen lyases. [5,844 PDB entries] EC 4.2.3.- Acting on phosphates. [489 PDB entries] EC 4.2.3.97 (-)-delta-cadinene synthase. [-]

Reaction:		(2E,6E)-farnesyl diphosphate = (-)-delta-cadinene + diphosphate.
		(2E,6E)-farnesyl diphosphate = (-)-delta-cadinene + diphosphate Molecule diagrams generated from .mol files obtained from the KEGG ftp site.
Comments:		The cyclization mechanism involves an intermediate nerolidyl diphosphate leading to a helminthogermacradienyl cation. Following a 1,3-hydride shift of the original 1-pro-S hydrogen of (2E,6E)-farnesyl diphosphate, cyclization and deprotonation gives (-)-delta-cadinene.
Links:		[IntEnz]   [ExPASy]   [KEGG]

There are no PDB entries in enzyme class E.C.4.2.3.97