EC 5.3.3.10 - 5-carboxymethyl-2-hydroxymuconate Δ-isomerase
IntEnz view
ENZYME view
IntEnz Enzyme Nomenclature
EC 5.3.3.10
Names
Accepted name:
5-carboxymethyl-2-hydroxymuconate Δ-isomerase
Other
names:
CHM isomerase
5-carboxymethyl-2-hydroxymuconic acid isomerase
5-carboxymethyl-2-hydroxymuconic acid isomerase
Systematic name:
5-carboxymethyl-2-hydroxymuconate Δ2,Δ4-2-oxo,Δ3-isomerase
Reaction
- 5-carboxymethyl-2-hydroxymuconate = (3E,5R)-5-carboxy-2-oxohept-3-enedioate
Comments:
Part of the homoprotocatechuate degradation pathway in Escherichia coli C.
Links to other databases
Enzymes and pathways:
NC-IUBMB
,
BRENDA
,
ExplorEnz
,
ENZYME@ExPASy
,
KEGG
,
MetaCyc
,
UM-BBD
,
UniPathway
Gene Ontology:
GO:0008704
UniProtKB/Swiss-Prot:
References
-
Identification and purification of distinct isomerase and decarboxylase enzymes involved in the 4-hydroxyphenylacetate catabolic pathway of Escherichia coli.Eur. J. Biochem. 117 : 581-584 (1981). [PMID: 7026235]
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Stereochemical studies of 5-(carboxymethyl)-2-hydroxymuconate isomerase and 5-(carboxymethyl)-2-oxo-3-hexene-1,6-dioate decarboxylase from Escherichia coli C: mechanistic and evolutionary implications.J. Am. Chem. Soc. 117 : 8719-8726 (1995).
[EC 5.3.3.10 created 1984]