EC 1 - Oxidoreductases
EC 1.1 - Acting on the CH-OH group of donors
EC 1.1.1 - With NAD+ or NADP+ as acceptor
EC 1.1.1.321 - Benzil reductase [(R)-benzoin forming]
IntEnz view
ENZYME view
IntEnz Enzyme Nomenclature
EC 1.1.1.321
Names
Accepted name:
benzil reductase [(R)-benzoin forming]
Systematic name:
(R)-benzoin:NADP+ oxidoreductase
Reaction
- (R)-benzoin + NADP+ = benzil + NADPH + H+
Comments:
The enzyme from the bacterium Xanthomonas oryzae is able to reduce enantioselectively only one of the two carbonyl groups of benzil to give optically active (R)-benzoin.
Links to other databases
References
-
Asymmetric reduction of benzil to benzoin catalyzed by the enzyme system of a microorganism.Chem. Lett. 14 : 1111-1112 (1985).
[EC 1.1.1.321 created 2012]