CHEBI:72703 - Boc-DON-Gln-Ile-Val-OMe

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ChEBI Name Boc-DON-Gln-Ile-Val-OMe
ChEBI ID CHEBI:72703
Definition A tetrapeptide comprising N-(tert-butoxycarbonyl)-6-diazo-5-oxo-L-norleucyl, L-glutaminyl, L-isoleucyl and methyl L-valinate residues coupled in sequence.
Stars This entity has been manually annotated by the ChEBI Team.
Submitter Sandra Orchard
Supplier Information
Download Molfile XML SDF
Formula C28H47N7O9
Net Charge 0
Average Mass 625.71430
Monoisotopic Mass 625.34353
InChI InChI=1S/C28H47N7O9/c1-9-16(4)22(25(40)34-21(15(2)3)26(41)43-8)35-24(39)18(12-13-20(29)37)32-23(38)19(11-10-17(36)14-31-30)33-27(42)44-28(5,6)7/h14-16,18-19,21-22H,9-13H2,1-8H3,(H2,29,37)(H,32,38)(H,33,42)(H,34,40)(H,35,39)/t16-,18-,19-,21-,22-/m0/s1
InChIKey PZEJVHJJSBKTSS-ITJSPEIASA-N
SMILES CC[C@H](C)[C@H](NC(=O)[C@H](CCC(N)=O)NC(=O)[C@H](CCC(=O)C=[N+]=[N-])NC(=O)OC(C)(C)C)C(=O)N[C@@H](C(C)C)C(=O)OC
Roles Classification
Chemical Role(s): Bronsted base
A molecular entity capable of accepting a hydron from a donor (Bronsted acid).
(via organic amino compound )
Biological Role(s): EC 2.3.2.13 (protein-glutamine gamma-glutamyltransferase) inhibitor
An EC 2.3.2.* (aminoacyltransferase) inhibitor that interferes with the action of protein-glutamine gamma-glutamyltransferase (EC 2.3.2.13).
View more via ChEBI Ontology
ChEBI Ontology
Outgoing Boc-DON-Gln-Ile-Val-OMe (CHEBI:72703) has role EC 2.3.2.13 (protein-glutamine γ-glutamyltransferase) inhibitor (CHEBI:72716)
Boc-DON-Gln-Ile-Val-OMe (CHEBI:72703) is a carbamate ester (CHEBI:23003)
Boc-DON-Gln-Ile-Val-OMe (CHEBI:72703) is a diazo compound (CHEBI:39444)
Boc-DON-Gln-Ile-Val-OMe (CHEBI:72703) is a methyl ester (CHEBI:25248)
Boc-DON-Gln-Ile-Val-OMe (CHEBI:72703) is a tetrapeptide (CHEBI:48030)
IUPAC Name
methyl N-(tert-butoxycarbonyl)-6-diazo-5-oxo-L-norleucyl-L-glutaminyl-L-isoleucyl-L-valinate
Synonyms Sources
Boc-Don ChEBI
BOC-DON-QIV-OMe ChEBI
Boc-L-DON-L-Gln-L-Ile-L-Val-OMe ChEBI
Registry Number Type Source
22280277 Reaxys Registry Number Reaxys
Citations Waiting for Citations Types Sources
18202319 PubMed citation Europe PMC
19353617 PubMed citation Europe PMC
22442151 PubMed citation SUBMITTER
Last Modified
03 March 2015