Figure 3 - full size

 

Figure 3.
Superposition of 16 trimeric N@d layers of known structure, including 3 exemplars from this study as listed in Table S1, all coordinating chloride. In 6 cases the polar network is extended by Thr in e of the neighboring chain and in 7 cases by Asn or Asp in g of the same chain, all with the same geometry as in SadAK3, including the bridging water molecule. Dimeric, tetrameric, and 2 further trimeric instances are shown in Fig. S2.