_EC 3.2.1.125 Raucaffricine beta-glucosidase. 5 PDB entries  
EC 3.-.-.- Hydrolases. [17,508 PDB entries]
EC 3.2.-.- Glycosylases. [3,469 PDB entries]
EC 3.2.1.- Glycosidases, i.e. enzymes hydrolyzing O- and S-glycosyl compound [3,025 PDB entries]
EC 3.2.1.125 Raucaffricine beta-glucosidase. [5 PDB entries]    
3u57

Pathway: Ajmaline, Vinorine, Vomilenine and Raucaffricine Biosynthesis
Reaction: Raucaffricine + H(2)O = D-glucose + vomilenine.
 


Raucaffricine
+ H(2)O
=
D-glucose
+
vomilenine
Molecule diagrams generated from .mol files obtained from the KEGG ftp site.

Comments: Highly specific; some other ajmalan glucoside alkaloids are hydrolyzed, more slowly.
Links:   [IntEnz]   [ExPASy]   [KEGG]  

There are 5 PDB entries in enzyme class E.C.3.2.1.125

  PDB code Protein
3u57
Structures of alkaloid biosynthetic glucosidases decode subs specificity
Source: Rauvolfia serpentina. Devilpepper. Organism_taxid: 4060. Expressed in: escherichia coli. Expression_system_taxid: 562
Chains: A, B (471 residues) CATH domain: 3.20.20.80
3u5u
Structures of alkaloid biosynthetic glucosidases decode subs specificity
Source: Rauvolfia serpentina. Devilpepper. Organism_taxid: 4060. Expressed in: escherichia coli. Expression_system_taxid: 562
Chains: A, B (470 residues) CATH domain: 3.20.20.80
3zj6
Crystal of raucaffricine glucosidase in complex with inhibit
Source: Rauvolfia serpentina. Serpentwood. Organism_taxid: 4060. Expressed in: escherichia coli m15. Expression_system_taxid: 1007065.
Chains: A, B (469 residues) CATH domain: 3.20.20.80
4atl
Crystal structure of raucaffricine glucosidase in complex wi glucose
Source: Rauvolfia serpentina. Serpentwood. Organism_taxid: 4060. Expressed in: escherichia coli. Expression_system_taxid: 562.
Chains: A, B (470 residues) CATH domain: 3.20.20.80
4ek7
High speed x-ray analysis of plant enzymes at room temperatu
Source: Rauvolfia serpentina. Devilpepper. Organism_taxid: 4060. Expressed in: escherichia coli. Expression_system_taxid: 562
Chains: A, B (470 residues) CATH domain: 3.20.20.80