_EC 2.7.8.23 Carboxyvinyl-carboxyphosphonate phosphorylmutase. 1 PDB entries  
EC 2.-.-.- Transferases. [15,100 PDB entries]
EC 2.7.-.- Transferring phosphorous-containing groups. [9,112 PDB entries]
EC 2.7.8.- Transferases for other substituted phosphate groups. [32 PDB entries]
EC 2.7.8.23 Carboxyvinyl-carboxyphosphonate phosphorylmutase. [1 PDB entries]    
2qiw

Reaction: 1-carboxyvinyl carboxyphosphonate = 3-(hydrohydroxyphosphoryl)pyruvate + CO(2).
 


1-carboxyvinyl carboxyphosphonate
=
3-(hydrohydroxyphosphoryl)pyruvate
+
CO(2)
Molecule diagrams generated from .mol files obtained from the KEGG ftp site.

Other name(s): Carboxyphosphonoenolpyruvate phosphonomutase. Cpep phosphonomutase.
Comments: Catalyzes the transfer and decarboxylation of the carboxy(hydroxy)phosphoryl group, HOOC-P(O)(OH)- (phosphoryl being a 3-valent group), in the formation of an unusual C-P bond that is involved in the biosynthesis of the antibiotic bialaphos.
Links:   [IntEnz]   [ExPASy]   [KEGG]  

There are 1 PDB entries in enzyme class E.C.2.7.8.23

  PDB code Protein
2qiw
Crystal structure of a putative phosphoenolpyruvate phosphon (ncgl1015, cgl1060) from corynebacterium glutamicum atcc 13 1.80 a resolution
Source: Corynebacterium glutamicum atcc 13032. Organism_taxid: 196627. Strain: dsm 20300, jcm 1318, lmg 3730, ncimb 10025. Gene: np_600288.1, cgl1060. Expressed in: escherichia coli. Expression_system_taxid: 562.
Chains: A, B (255 residues) CATH domains: 3.20.20.60 1.20.5.510
Bound ligand:   Het Group GOL is 50.00% similar to enzyme product 3-(hydrohydroxyphosphoryl)pyruvate