_EC 1.2.1.58 Phenylglyoxylate dehydrogenase (acylating). 0 PDB entries  
EC 1.-.-.- Oxidoreductases. [8,663 PDB entries]
EC 1.2.-.- Acting on the aldehyde or oxo group of donors. [499 PDB entries]
EC 1.2.1.- With NAD(+) or NADP(+) as acceptor. [369 PDB entries]
EC 1.2.1.58 Phenylglyoxylate dehydrogenase (acylating). [-]    

Reaction: Phenylglyoxylate + NAD(+) + CoA = benzoyl-S-CoA + CO(2) + Nadh.
 


Phenylglyoxylate
+
NAD(+)
+
CoA
= benzoyl-S-CoA
+
CO(2)
+
NADH
Molecule diagrams generated from .mol files obtained from the KEGG ftp site.

Cofactor(s): FAD; Iron-sulfur; Thiamine diphosphate.
 

FAD

Iron-sulfur

Thiamine diphosphate
Molecule diagrams generated from .mol files obtained from the KEGG ftp site.
Comments: The enzyme from Azoarcus evansii is specific for phenylglyoxylate. 2-oxoisovalerate is oxidized at 15% of the rate for phenylglyoxylate. Also reduces viologen dyes.
Links:   [IntEnz]   [ExPASy]   [KEGG]  

There are no PDB entries in enzyme class E.C.1.2.1.58