_EC 1.14.99.40 5,6-dimethylbenzimidazole synthase. 0 PDB entries  
EC 1.-.-.- Oxidoreductases. [8,653 PDB entries]
EC 1.14.-.- Acting on paired donors, with incorporation or reduction of molecu [1,428 PDB entries]
EC 1.14.99.- Miscellaneous (requires further characterization). [145 PDB entries]
EC 1.14.99.40 5,6-dimethylbenzimidazole synthase. [-]    

Reaction: FMNH(2) + Nadh + O(2) = 5,6-dimethylbenzimidazole + D-erythrose 4-phosphate + NAD(+) + other product.
 


FMNH(2)
+
NADH
+
O(2)
=
5,6-dimethylbenzimidazole
+
D-erythrose 4-phosphate
+
NAD(+)
+ other product
Molecule diagrams generated from .mol files obtained from the KEGG ftp site.

Comments: The C-2 of 5,6-dimethylbenzimidazole is derived from C-1' of the ribityl group of FMNH(2) and 2-H from the ribityl 1'-pro-(S) hydrogen. The other product may be barbituric acid. The stoichiometery of the reaction is not known.
Links:   [IntEnz]   [ExPASy]   [KEGG]  

There are no PDB entries in enzyme class E.C.1.14.99.40