spacer

Entry M0132    1.14.14.3    alkanal monooxygenase (FMN-linked)

Next Step

Step 01

FMN undergoes a double bond rearrangement that results in the single electron transfer from FMN to dioxygen and a proton transfer from an unidentified base to the dioxygen molecule.

GIF of Reaction Step M0132.stg01



Mechanisms

Electron Transfer
Radical Formation
Proton Transfer

Mechanism Components

Overall Reactant Used
Bond Formation
Bond Cleavage
Bond Order Change
Intermediate Formation

Amino acids involved in the reaction step.

Amino Acid Location of Function Activity Function
His44 Side Chain spectator Not Active
His45 Side Chain spectator Electrostatic Stabiliser
Polar Non-polar interaction

Reactive Centre

Bonds Formed Bonds Cleaved Bonds Changed in Order Atom Types Involved
O-H
R-H
The C-N bond changes from a single to double bond
The C-C bond changes from a double to single bond
The O-O bond changes from a double to single bond
C
H
N
O
R

View similar reactions in MACiE.


spacer
spacer