Entry M0107 22.214.171.124 carbon-monoxide dehydrogenase (acceptor)
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Water initiates a nucleophilic attack on the Mo(IV) centre, displacing the negatively charged oxygen of the carboxylate group in a substitution reaction, which initiates an elimination of the sulfur group, to reform the bridging sulfur dianion and the formation of carbon dioxide, which decoordinates from the metal centre.
Amino acids involved in the reaction step.
Organic Cofactors involved in the reaction step
Metal Cofactors involved in Step 05
||Bonds Changed in Order
||Atom Types Involved
The C-O bond changes from a single to double bond
View similar reactions in MACiE.