Entry M0107 184.108.40.206 carbon-monoxide dehydrogenase (acceptor)
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The carbonyl oxygen initiates a nucleophilic attack on the Cu(I) centre in a substitution reaction that displaces the bridging sulfur ligand from the Cu(I) centre.
Comment: The ligand substitution at the Cu is presumably reinforced by relaxing the tensed state of the oxidised cluster through the retraction of Cys-388 .
Amino acids involved in the reaction step.
Organic Cofactors involved in the reaction step
Metal Cofactors involved in Step 04
||Bonds Changed in Order
||Atom Types Involved
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