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CHEBI:60052 - siroheme(8−)

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ChEBI Name siroheme(8−)
ChEBI ID CHEBI:60052
ChEBI ASCII Name siroheme(8-)
Definition A cyclic tetrapyrrole anion obtained by deprotonation of the carboxy groups of siroheme; major species at pH 7.3.
Stars This entity has been manually annotated by the ChEBI Team.
Submitter Kristian Axelsen
Supplier Information
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Formula C42H36FeN4O16
Net Charge -8
Average Mass 908.59700
Monoisotopic Mass 908.148
InChI InChI=1S/C42H46N4O16.Fe/c1-41(17-39(59)60)23(5-9-35(51)52)29-14-27-21(11-37(55)56)19(3-7-33(47)48)25(43-27)13-26-20(4-8-34(49)50)22(12-38(57)58)28(44-26)15-31-42(2,18-40(61)62)24(6-10-36(53)54)30(46-31)16-32(41)45-29;/h13-16,23-24H,3-12,17-18H2,1-2H3,(H10,43,44,45,46,47,48,49,50,51,52,53,54,55,56,57,58,59,60,61,62);/q;+2/p-10/t23-,24-,41+,42+;/m1./s1
InChIKey DLKSSIHHLYNIKN-QIISWYHFSA-D
SMILES C[C@]1(CC([O-])=O)[C@H](CCC([O-])=O)C2=CC3=[N+]4C(=Cc5c(CC([O-])=O)c(CCC([O-])=O)c6C=C7C(CCC([O-])=O)=C(CC([O-])=O)C8=[N+]7[Fe--]4(N2C1=C8)n56)[C@@H](CCC([O-])=O)[C@]3(C)CC([O-])=O
Metabolite of Species Details
Saccharomyces cerevisiae (NCBI:4932) Source: yeast.sf.net See: PubMed
Roles Classification
Biological Role(s): Saccharomyces cerevisiae metabolite
Any fungal metabolite produced during a metabolic reaction in Baker's yeast (Saccharomyces cerevisiae ).
metabolite
Any intermediate or product resulting from metabolism. The term 'metabolite' subsumes the classes commonly known as primary and secondary metabolites.
(via heme )
prosthetic group
A tightly bound, specific nonpolypeptide unit in a protein determining and involved in its biological activity.
(via heme )
cofactor
An organic molecule or ion (usually a metal ion) that is required by an enzyme for its activity. It may be attached either loosely (coenzyme) or tightly (prosthetic group).
(via porphyrins )
View more via ChEBI Ontology
ChEBI Ontology
Outgoing siroheme(8−) (CHEBI:60052) has role Saccharomyces cerevisiae metabolite (CHEBI:75772)
siroheme(8−) (CHEBI:60052) is a cyclic tetrapyrrole anion (CHEBI:58941)
siroheme(8−) (CHEBI:60052) is a heme (CHEBI:30413)
siroheme(8−) (CHEBI:60052) is conjugate base of siroheme (CHEBI:28599)
Incoming siroheme (CHEBI:28599) is conjugate acid of siroheme(8−) (CHEBI:60052)
IUPAC Name
[3,3',3'',3'''-[(7S,8S,12S,13S)-3,8,13,17-tetrakis(carboxymethyl)-8,13-dimethyl-7,8,12,13-tetrahydroporphyrin-2,7,12,18-tetrayl-κN21N22N23N24]tetrapropanoato(10−)]ferrate(6−)
Synonyms Sources
siroheme UniProt
siroheme hexaanion ChEBI
Last Modified
21 January 2016
Submitter Remark
2010-08-12 20:23:01.0 Kristian Axelsen MetaCyc link: SIROHEME