Ketcher 10162309512D 1   1.00000     0.00000     0

 21 23  0     0  0            999 V2000
   17.6820   -6.9817    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   16.8160   -6.4817    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   15.9500   -6.9817    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   15.0839   -6.4817    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   14.2179   -6.9817    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   13.3519   -6.4817    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
   12.4858   -6.9817    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   12.4858   -7.9817    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   11.6198   -8.4817    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   10.7538   -7.9817    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   10.7538   -6.9817    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   11.6198   -6.4817    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    9.8878   -6.4817    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    9.0218   -6.9817    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   13.3519   -8.4817    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   14.2179   -7.9817    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   15.0839   -8.4817    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   15.9500   -7.9817    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
   16.8160   -8.4817    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   15.0839   -9.4817    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   15.9500   -9.9817    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0     0  0
  2  3  1  0     0  0
  3  4  2  0     0  0
  4  5  1  0     0  0
  5  6  2  0     0  0
  6  7  1  0     0  0
  7  8  2  0     0  0
  8  9  1  0     0  0
  9 10  2  0     0  0
 10 11  1  0     0  0
 11 12  2  0     0  0
 12  7  1  0     0  0
 11 13  1  0     0  0
 13 14  1  0     0  0
  8 15  1  0     0  0
 15 16  1  0     0  0
 16  5  1  0     0  0
 16 17  2  0     0  0
 17 18  1  0     0  0
 18  3  1  0     0  0
 18 19  2  0     0  0
 17 20  1  0     0  0
 20 21  1  0     0  0
M  END
> <ID>
CHEBI:197443

> <NAME>
michigazone

> <DEFINITION>
A member of the class phenoxazines that is 3H-phenoxazine substituted by methoxy, oxo, methoxy and hydroxymethyl groups at positions 2, 3, 4 and 8, respectively. It is a red pigment produced by the soil bacterium Streptomyces michiganensis.

> <STAR>
3

> <SYNONYM>
Michigazon; 8-hydroxymethyl-2,4-dimethoxy-3H-phenoxazine-3-one

> <IUPAC_NAME>
8-(hydroxymethyl)-2,4-dimethoxy-3H-phenoxazin-3-one

> <FORMULA>
C15H13NO5

> <MASS>
287.271

> <MONOISOTOPIC_MASS>
287.07937

> <CHARGE>
0

> <SMILES>
COC1=CC2=NC3=C(OC2=C(OC)C1=O)C=CC(CO)=C3

> <INCHI>
InChI=1S/C15H13NO5/c1-19-12-6-10-14(15(20-2)13(12)18)21-11-4-3-8(7-17)5-9(11)16-10/h3-6,17H,7H2,1-2H3

> <INCHIKEY>
DSDZKWZYXPNNCJ-UHFFFAOYSA-N

> <CAS_REGISTRY_NUMBER>
62267-63-4

> <PUBMED_CITATION>
814873; 8626249

$$$$