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GO:1900812 helvolic acid biosynthetic process

Term Information

ID GO:1900812
Name helvolic acid biosynthetic process
Ontology Biological Process
Definition The chemical reactions and pathways resulting in the formation of helvolic acid.
GONUTS GO:1900812 Wiki Page

Synonyms

Synonyms are alternative words or phrases closely related in meaning to the term name, with indication of the relationship between the name and synonym given by the synonym scope. Click on the icon for more details.
Type Synonym
related Fumigacin formation
exact helvolic acid anabolism
exact helvolic acid biosynthesis
exact helvolic acid synthesis
related Fumigacin biosynthetic process
related Fumigacin biosynthesis
related Fumigacin anabolism
exact helvolic acid formation
related Fumigacin synthesis

Cross-Ontology Relations

Relation Other Ontology ID Term
has_output CHEBI CHEBI:62460 helvolic acid

Ancestor Chart

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Child Terms

This table lists all terms that are direct descendants (child terms) of GO:1900812:
Relationship To GO:1900812 Child Term Child Term Name
Regulates GO:1900840 regulation of helvolic acid biosynthetic process
Negatively regulates GO:1900841 negative regulation of helvolic acid biosynthetic process
Positively regulates GO:1900842 positive regulation of helvolic acid biosynthetic process

Protein Annotation

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GO Term Name
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Co-occurring Terms

These tables show the number of times the term listed in the table has been co-annotated with GO:1900812. The terms are listed in descending order of number of times the term has been co-annotated.
The table on the left is calculated using both electronic and manual-evidenced annotations, while the table on the right is calculated using only manual-evidenced annotations.
Co-occurrence statistics for GO:1900812 based on the entire annotation set Co-occurrence statistics for GO:1900812 based on non-IEA annotations only

Change Log

All changes

Timestamp Action Category Detail
2014-03-07 Added RELATION is a GO:0042181 (ketone biosynthetic process)
2014-01-16 Added RELATION is a GO:0072330 (monocarboxylic acid biosynthetic process)
2014-01-16 Deleted RELATION is a GO:0046394 (carboxylic acid biosynthetic process)
2012-10-19 Added RELATION is a GO:0044550 (secondary metabolite biosynthetic process)
2012-06-12 Deleted SYNONYM InChI=1S/C33H44O8/c1-17(2)10-9-11-21(30(38)39)26-22-12-13-25-31(6)15-14-23(36)18(3)27(31)28(41-20(5)35)29(37)33(25,8)32(22,7)16-24(26)40-19(4)34/h10,14-15,18,22,24-25,27-28H,9,11-13,16H2,1-8H3,(H,38,39)/b26-21-/t18-,22+,24+,25+,27-,28+,31-,32+,33-/m1/s1 synthesis
2012-06-12 Deleted SYNONYM (4alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17beta)-6,16- bis(acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid anabolism
2012-06-12 Deleted SYNONYM InChIKey=MDFZYGLOIJNNRM-OAJDADRGSA-N anabolism
2012-06-12 Deleted SYNONYM (4alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17beta)-6,16- bis(acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid biosynthesis
2012-06-12 Deleted SYNONYM C33H44O8 anabolism
2012-06-12 Deleted SYNONYM (4alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17beta)-6,16- bis(acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid synthesis
2012-06-12 Deleted SYNONYM 16-(Acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid anabolism
2012-06-12 Deleted SYNONYM C33H44O8 biosynthesis
2012-06-12 Deleted SYNONYM InChIKey=MDFZYGLOIJNNRM-OAJDADRGSA-N synthesis
2012-06-12 Deleted SYNONYM (4alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17beta)-6,16- bis(acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid formation
2012-06-12 Deleted SYNONYM 16-(Acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid biosynthesis
2012-06-12 Deleted SYNONYM InChI=1S/C33H44O8/c1-17(2)10-9-11-21(30(38)39)26-22-12-13-25-31(6)15-14-23(36)18(3)27(31)28(41-20(5)35)29(37)33(25,8)32(22,7)16-24(26)40-19(4)34/h10,14-15,18,22,24-25,27-28H,9,11-13,16H2,1-8H3,(H,38,39)/b26-21-/t18-,22+,24+,25+,27-,28+,31-,32+,33-/m1/s1 biosynthetic process
2012-06-12 Deleted SYNONYM InChIKey=MDFZYGLOIJNNRM-OAJDADRGSA-N formation
2012-06-12 Deleted SYNONYM InChIKey=MDFZYGLOIJNNRM-OAJDADRGSA-N biosynthesis
2012-06-12 Deleted SYNONYM 16-(Acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid synthesis
2012-06-12 Deleted SYNONYM InChI=1S/C33H44O8/c1-17(2)10-9-11-21(30(38)39)26-22-12-13-25-31(6)15-14-23(36)18(3)27(31)28(41-20(5)35)29(37)33(25,8)32(22,7)16-24(26)40-19(4)34/h10,14-15,18,22,24-25,27-28H,9,11-13,16H2,1-8H3,(H,38,39)/b26-21-/t18-,22+,24+,25+,27-,28+,31-,32+,33-/m1/s1 anabolism
2012-06-12 Deleted SYNONYM (2Z)-2-[(4alpha,5alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17Z)-6,16-diacetoxy-4,8,10,14-tetramethyl-3,7-dioxogon-1-en-17-ylidene]-6-methylhept-5-enoic acid synthesis
2012-06-12 Deleted SYNONYM InChIKey=MDFZYGLOIJNNRM-OAJDADRGSA-N biosynthetic process
2012-06-12 Deleted SYNONYM C33H44O8 formation
2012-06-12 Deleted SYNONYM [H][C@@]12CC[C@@]3([H])[C@@]4(C)C=CC(=O)[C@@H](C)[C@]4([H])[C@H](OC(C)=O)C(=O)[C@]3(C)[C@@]1(C)C[C@H](OC(C)=O)C2=C(CCC=C(C)C)C(O)=O synthesis
2012-06-12 Deleted SYNONYM (2Z)-2-[(4alpha,5alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17Z)-6,16-diacetoxy-4,8,10,14-tetramethyl-3,7-dioxogon-1-en-17-ylidene]-6-methylhept-5-enoic acid formation
2012-06-12 Deleted SYNONYM 16-(Acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid formation
2012-06-12 Deleted SYNONYM InChI=1S/C33H44O8/c1-17(2)10-9-11-21(30(38)39)26-22-12-13-25-31(6)15-14-23(36)18(3)27(31)28(41-20(5)35)29(37)33(25,8)32(22,7)16-24(26)40-19(4)34/h10,14-15,18,22,24-25,27-28H,9,11-13,16H2,1-8H3,(H,38,39)/b26-21-/t18-,22+,24+,25+,27-,28+,31-,32+,33-/m1/s1 biosynthesis
2012-06-12 Deleted SYNONYM (2Z)-2-[(4alpha,5alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17Z)-6,16-diacetoxy-4,8,10,14-tetramethyl-3,7-dioxogon-1-en-17-ylidene]-6-methylhept-5-enoic acid anabolism
2012-06-12 Deleted SYNONYM (2Z)-2-[(4alpha,5alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17Z)-6,16-diacetoxy-4,8,10,14-tetramethyl-3,7-dioxogon-1-en-17-ylidene]-6-methylhept-5-enoic acid biosynthetic process
2012-06-12 Deleted SYNONYM InChI=1S/C33H44O8/c1-17(2)10-9-11-21(30(38)39)26-22-12-13-25-31(6)15-14-23(36)18(3)27(31)28(41-20(5)35)29(37)33(25,8)32(22,7)16-24(26)40-19(4)34/h10,14-15,18,22,24-25,27-28H,9,11-13,16H2,1-8H3,(H,38,39)/b26-21-/t18-,22+,24+,25+,27-,28+,31-,32+,33-/m1/s1 formation
2012-06-12 Deleted SYNONYM 16-(Acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid biosynthetic process
2012-06-12 Deleted SYNONYM (4alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17beta)-6,16- bis(acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid biosynthetic process
2012-06-12 Deleted SYNONYM [H][C@@]12CC[C@@]3([H])[C@@]4(C)C=CC(=O)[C@@H](C)[C@]4([H])[C@H](OC(C)=O)C(=O)[C@]3(C)[C@@]1(C)C[C@H](OC(C)=O)C2=C(CCC=C(C)C)C(O)=O biosynthesis
2012-06-12 Deleted SYNONYM [H][C@@]12CC[C@@]3([H])[C@@]4(C)C=CC(=O)[C@@H](C)[C@]4([H])[C@H](OC(C)=O)C(=O)[C@]3(C)[C@@]1(C)C[C@H](OC(C)=O)C2=C(CCC=C(C)C)C(O)=O biosynthetic process
2012-06-12 Deleted SYNONYM (2Z)-2-[(4alpha,5alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17Z)-6,16-diacetoxy-4,8,10,14-tetramethyl-3,7-dioxogon-1-en-17-ylidene]-6-methylhept-5-enoic acid biosynthesis
2012-06-12 Deleted SYNONYM C33H44O8 biosynthetic process
2012-06-12 Deleted SYNONYM C33H44O8 synthesis
2012-06-12 Deleted SYNONYM [H][C@@]12CC[C@@]3([H])[C@@]4(C)C=CC(=O)[C@@H](C)[C@]4([H])[C@H](OC(C)=O)C(=O)[C@]3(C)[C@@]1(C)C[C@H](OC(C)=O)C2=C(CCC=C(C)C)C(O)=O anabolism
2012-06-12 Deleted SYNONYM [H][C@@]12CC[C@@]3([H])[C@@]4(C)C=CC(=O)[C@@H](C)[C@]4([H])[C@H](OC(C)=O)C(=O)[C@]3(C)[C@@]1(C)C[C@H](OC(C)=O)C2=C(CCC=C(C)C)C(O)=O formation
2012-06-07 Added TERM helvolic acid biosynthetic process
2012-06-07 Added DEFINITION The chemical reactions and pathways resulting in the formation of helvolic acid.
2012-06-07 Added SYNONYM (2Z)-2-[(4alpha,5alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17Z)-6,16-diacetoxy-4,8,10,14-tetramethyl-3,7-dioxogon-1-en-17-ylidene]-6-methylhept-5-enoic acid biosynthetic process
2012-06-07 Added SYNONYM 16-(Acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid biosynthesis
2012-06-07 Added SYNONYM 16-(Acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid formation
2012-06-07 Added SYNONYM Fumigacin synthesis
2012-06-07 Added SYNONYM InChIKey=MDFZYGLOIJNNRM-OAJDADRGSA-N formation
2012-06-07 Added SYNONYM helvolic acid anabolism
2012-06-07 Added SYNONYM (4alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17beta)-6,16- bis(acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid anabolism
2012-06-07 Added SYNONYM (4alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17beta)-6,16- bis(acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid formation
2012-06-07 Added SYNONYM C33H44O8 biosynthesis
2012-06-07 Added SYNONYM InChI=1S/C33H44O8/c1-17(2)10-9-11-21(30(38)39)26-22-12-13-25-31(6)15-14-23(36)18(3)27(31)28(41-20(5)35)29(37)33(25,8)32(22,7)16-24(26)40-19(4)34/h10,14-15,18,22,24-25,27-28H,9,11-13,16H2,1-8H3,(H,38,39)/b26-21-/t18-,22+,24+,25+,27-,28+,31-,32+,33-/m1/s1 synthesis
2012-06-07 Added SYNONYM InChIKey=MDFZYGLOIJNNRM-OAJDADRGSA-N biosynthesis
2012-06-07 Added SYNONYM InChIKey=MDFZYGLOIJNNRM-OAJDADRGSA-N biosynthetic process
2012-06-07 Added SYNONYM 16-(Acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid anabolism
2012-06-07 Added SYNONYM C33H44O8 anabolism
2012-06-07 Added SYNONYM C33H44O8 biosynthetic process
2012-06-07 Added SYNONYM InChI=1S/C33H44O8/c1-17(2)10-9-11-21(30(38)39)26-22-12-13-25-31(6)15-14-23(36)18(3)27(31)28(41-20(5)35)29(37)33(25,8)32(22,7)16-24(26)40-19(4)34/h10,14-15,18,22,24-25,27-28H,9,11-13,16H2,1-8H3,(H,38,39)/b26-21-/t18-,22+,24+,25+,27-,28+,31-,32+,33-/m1/s1 biosynthetic process
2012-06-07 Added SYNONYM InChIKey=MDFZYGLOIJNNRM-OAJDADRGSA-N anabolism
2012-06-07 Added SYNONYM [H][C@@]12CC[C@@]3([H])[C@@]4(C)C=CC(=O)[C@@H](C)[C@]4([H])[C@H](OC(C)=O)C(=O)[C@]3(C)[C@@]1(C)C[C@H](OC(C)=O)C2=C(CCC=C(C)C)C(O)=O biosynthesis
2012-06-07 Added SYNONYM 16-(Acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid synthesis
2012-06-07 Added SYNONYM (4alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17beta)-6,16- bis(acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid biosynthetic process
2012-06-07 Added SYNONYM (4alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17beta)-6,16- bis(acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid synthesis
2012-06-07 Added SYNONYM 16-(Acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid biosynthetic process
2012-06-07 Added SYNONYM InChI=1S/C33H44O8/c1-17(2)10-9-11-21(30(38)39)26-22-12-13-25-31(6)15-14-23(36)18(3)27(31)28(41-20(5)35)29(37)33(25,8)32(22,7)16-24(26)40-19(4)34/h10,14-15,18,22,24-25,27-28H,9,11-13,16H2,1-8H3,(H,38,39)/b26-21-/t18-,22+,24+,25+,27-,28+,31-,32+,33-/m1/s1 anabolism
2012-06-07 Added SYNONYM InChI=1S/C33H44O8/c1-17(2)10-9-11-21(30(38)39)26-22-12-13-25-31(6)15-14-23(36)18(3)27(31)28(41-20(5)35)29(37)33(25,8)32(22,7)16-24(26)40-19(4)34/h10,14-15,18,22,24-25,27-28H,9,11-13,16H2,1-8H3,(H,38,39)/b26-21-/t18-,22+,24+,25+,27-,28+,31-,32+,33-/m1/s1 biosynthesis
2012-06-07 Added SYNONYM helvolic acid biosynthesis
2012-06-07 Added SYNONYM Fumigacin formation
2012-06-07 Added SYNONYM InChI=1S/C33H44O8/c1-17(2)10-9-11-21(30(38)39)26-22-12-13-25-31(6)15-14-23(36)18(3)27(31)28(41-20(5)35)29(37)33(25,8)32(22,7)16-24(26)40-19(4)34/h10,14-15,18,22,24-25,27-28H,9,11-13,16H2,1-8H3,(H,38,39)/b26-21-/t18-,22+,24+,25+,27-,28+,31-,32+,33-/m1/s1 formation
2012-06-07 Added SYNONYM [H][C@@]12CC[C@@]3([H])[C@@]4(C)C=CC(=O)[C@@H](C)[C@]4([H])[C@H](OC(C)=O)C(=O)[C@]3(C)[C@@]1(C)C[C@H](OC(C)=O)C2=C(CCC=C(C)C)C(O)=O anabolism
2012-06-07 Added SYNONYM (4alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17beta)-6,16- bis(acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid biosynthesis
2012-06-07 Added SYNONYM C33H44O8 formation
2012-06-07 Added SYNONYM C33H44O8 synthesis
2012-06-07 Added SYNONYM Fumigacin anabolism
2012-06-07 Added SYNONYM Fumigacin biosynthesis
2012-06-07 Added SYNONYM Fumigacin biosynthetic process
2012-06-07 Added SYNONYM InChIKey=MDFZYGLOIJNNRM-OAJDADRGSA-N synthesis
2012-06-07 Added SYNONYM [H][C@@]12CC[C@@]3([H])[C@@]4(C)C=CC(=O)[C@@H](C)[C@]4([H])[C@H](OC(C)=O)C(=O)[C@]3(C)[C@@]1(C)C[C@H](OC(C)=O)C2=C(CCC=C(C)C)C(O)=O biosynthetic process
2012-06-07 Added SYNONYM helvolic acid synthesis
2012-06-07 Added SYNONYM (2Z)-2-[(4alpha,5alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17Z)-6,16-diacetoxy-4,8,10,14-tetramethyl-3,7-dioxogon-1-en-17-ylidene]-6-methylhept-5-enoic acid anabolism
2012-06-07 Added SYNONYM (2Z)-2-[(4alpha,5alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17Z)-6,16-diacetoxy-4,8,10,14-tetramethyl-3,7-dioxogon-1-en-17-ylidene]-6-methylhept-5-enoic acid biosynthesis
2012-06-07 Added SYNONYM (2Z)-2-[(4alpha,5alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17Z)-6,16-diacetoxy-4,8,10,14-tetramethyl-3,7-dioxogon-1-en-17-ylidene]-6-methylhept-5-enoic acid formation
2012-06-07 Added SYNONYM (2Z)-2-[(4alpha,5alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17Z)-6,16-diacetoxy-4,8,10,14-tetramethyl-3,7-dioxogon-1-en-17-ylidene]-6-methylhept-5-enoic acid synthesis
2012-06-07 Added SYNONYM [H][C@@]12CC[C@@]3([H])[C@@]4(C)C=CC(=O)[C@@H](C)[C@]4([H])[C@H](OC(C)=O)C(=O)[C@]3(C)[C@@]1(C)C[C@H](OC(C)=O)C2=C(CCC=C(C)C)C(O)=O formation
2012-06-07 Added SYNONYM [H][C@@]12CC[C@@]3([H])[C@@]4(C)C=CC(=O)[C@@H](C)[C@]4([H])[C@H](OC(C)=O)C(=O)[C@]3(C)[C@@]1(C)C[C@H](OC(C)=O)C2=C(CCC=C(C)C)C(O)=O synthesis
2012-06-07 Added SYNONYM helvolic acid formation
2012-06-07 Added RELATION is a GO:1900810 (helvolic acid metabolic process)
2012-06-07 Added RELATION is a GO:0046394 (carboxylic acid biosynthetic process)
2012-06-07 Added RELATION is a GO:0006694 (steroid biosynthetic process)

Term

Timestamp Action Category Detail
2012-06-07 Added TERM helvolic acid biosynthetic process

Definition/synonyms

Timestamp Action Category Detail
2012-06-12 Deleted SYNONYM InChI=1S/C33H44O8/c1-17(2)10-9-11-21(30(38)39)26-22-12-13-25-31(6)15-14-23(36)18(3)27(31)28(41-20(5)35)29(37)33(25,8)32(22,7)16-24(26)40-19(4)34/h10,14-15,18,22,24-25,27-28H,9,11-13,16H2,1-8H3,(H,38,39)/b26-21-/t18-,22+,24+,25+,27-,28+,31-,32+,33-/m1/s1 synthesis
2012-06-12 Deleted SYNONYM (4alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17beta)-6,16- bis(acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid anabolism
2012-06-12 Deleted SYNONYM InChIKey=MDFZYGLOIJNNRM-OAJDADRGSA-N anabolism
2012-06-12 Deleted SYNONYM (4alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17beta)-6,16- bis(acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid biosynthesis
2012-06-12 Deleted SYNONYM C33H44O8 anabolism
2012-06-12 Deleted SYNONYM (4alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17beta)-6,16- bis(acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid synthesis
2012-06-12 Deleted SYNONYM 16-(Acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid anabolism
2012-06-12 Deleted SYNONYM C33H44O8 biosynthesis
2012-06-12 Deleted SYNONYM InChIKey=MDFZYGLOIJNNRM-OAJDADRGSA-N synthesis
2012-06-12 Deleted SYNONYM (4alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17beta)-6,16- bis(acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid formation
2012-06-12 Deleted SYNONYM 16-(Acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid biosynthesis
2012-06-12 Deleted SYNONYM InChI=1S/C33H44O8/c1-17(2)10-9-11-21(30(38)39)26-22-12-13-25-31(6)15-14-23(36)18(3)27(31)28(41-20(5)35)29(37)33(25,8)32(22,7)16-24(26)40-19(4)34/h10,14-15,18,22,24-25,27-28H,9,11-13,16H2,1-8H3,(H,38,39)/b26-21-/t18-,22+,24+,25+,27-,28+,31-,32+,33-/m1/s1 biosynthetic process
2012-06-12 Deleted SYNONYM InChIKey=MDFZYGLOIJNNRM-OAJDADRGSA-N formation
2012-06-12 Deleted SYNONYM InChIKey=MDFZYGLOIJNNRM-OAJDADRGSA-N biosynthesis
2012-06-12 Deleted SYNONYM 16-(Acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid synthesis
2012-06-12 Deleted SYNONYM InChI=1S/C33H44O8/c1-17(2)10-9-11-21(30(38)39)26-22-12-13-25-31(6)15-14-23(36)18(3)27(31)28(41-20(5)35)29(37)33(25,8)32(22,7)16-24(26)40-19(4)34/h10,14-15,18,22,24-25,27-28H,9,11-13,16H2,1-8H3,(H,38,39)/b26-21-/t18-,22+,24+,25+,27-,28+,31-,32+,33-/m1/s1 anabolism
2012-06-12 Deleted SYNONYM (2Z)-2-[(4alpha,5alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17Z)-6,16-diacetoxy-4,8,10,14-tetramethyl-3,7-dioxogon-1-en-17-ylidene]-6-methylhept-5-enoic acid synthesis
2012-06-12 Deleted SYNONYM InChIKey=MDFZYGLOIJNNRM-OAJDADRGSA-N biosynthetic process
2012-06-12 Deleted SYNONYM C33H44O8 formation
2012-06-12 Deleted SYNONYM [H][C@@]12CC[C@@]3([H])[C@@]4(C)C=CC(=O)[C@@H](C)[C@]4([H])[C@H](OC(C)=O)C(=O)[C@]3(C)[C@@]1(C)C[C@H](OC(C)=O)C2=C(CCC=C(C)C)C(O)=O synthesis
2012-06-12 Deleted SYNONYM (2Z)-2-[(4alpha,5alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17Z)-6,16-diacetoxy-4,8,10,14-tetramethyl-3,7-dioxogon-1-en-17-ylidene]-6-methylhept-5-enoic acid formation
2012-06-12 Deleted SYNONYM 16-(Acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid formation
2012-06-12 Deleted SYNONYM InChI=1S/C33H44O8/c1-17(2)10-9-11-21(30(38)39)26-22-12-13-25-31(6)15-14-23(36)18(3)27(31)28(41-20(5)35)29(37)33(25,8)32(22,7)16-24(26)40-19(4)34/h10,14-15,18,22,24-25,27-28H,9,11-13,16H2,1-8H3,(H,38,39)/b26-21-/t18-,22+,24+,25+,27-,28+,31-,32+,33-/m1/s1 biosynthesis
2012-06-12 Deleted SYNONYM (2Z)-2-[(4alpha,5alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17Z)-6,16-diacetoxy-4,8,10,14-tetramethyl-3,7-dioxogon-1-en-17-ylidene]-6-methylhept-5-enoic acid anabolism
2012-06-12 Deleted SYNONYM (2Z)-2-[(4alpha,5alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17Z)-6,16-diacetoxy-4,8,10,14-tetramethyl-3,7-dioxogon-1-en-17-ylidene]-6-methylhept-5-enoic acid biosynthetic process
2012-06-12 Deleted SYNONYM InChI=1S/C33H44O8/c1-17(2)10-9-11-21(30(38)39)26-22-12-13-25-31(6)15-14-23(36)18(3)27(31)28(41-20(5)35)29(37)33(25,8)32(22,7)16-24(26)40-19(4)34/h10,14-15,18,22,24-25,27-28H,9,11-13,16H2,1-8H3,(H,38,39)/b26-21-/t18-,22+,24+,25+,27-,28+,31-,32+,33-/m1/s1 formation
2012-06-12 Deleted SYNONYM 16-(Acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid biosynthetic process
2012-06-12 Deleted SYNONYM (4alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17beta)-6,16- bis(acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid biosynthetic process
2012-06-12 Deleted SYNONYM [H][C@@]12CC[C@@]3([H])[C@@]4(C)C=CC(=O)[C@@H](C)[C@]4([H])[C@H](OC(C)=O)C(=O)[C@]3(C)[C@@]1(C)C[C@H](OC(C)=O)C2=C(CCC=C(C)C)C(O)=O biosynthesis
2012-06-12 Deleted SYNONYM [H][C@@]12CC[C@@]3([H])[C@@]4(C)C=CC(=O)[C@@H](C)[C@]4([H])[C@H](OC(C)=O)C(=O)[C@]3(C)[C@@]1(C)C[C@H](OC(C)=O)C2=C(CCC=C(C)C)C(O)=O biosynthetic process
2012-06-12 Deleted SYNONYM (2Z)-2-[(4alpha,5alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17Z)-6,16-diacetoxy-4,8,10,14-tetramethyl-3,7-dioxogon-1-en-17-ylidene]-6-methylhept-5-enoic acid biosynthesis
2012-06-12 Deleted SYNONYM C33H44O8 biosynthetic process
2012-06-12 Deleted SYNONYM C33H44O8 synthesis
2012-06-12 Deleted SYNONYM [H][C@@]12CC[C@@]3([H])[C@@]4(C)C=CC(=O)[C@@H](C)[C@]4([H])[C@H](OC(C)=O)C(=O)[C@]3(C)[C@@]1(C)C[C@H](OC(C)=O)C2=C(CCC=C(C)C)C(O)=O anabolism
2012-06-12 Deleted SYNONYM [H][C@@]12CC[C@@]3([H])[C@@]4(C)C=CC(=O)[C@@H](C)[C@]4([H])[C@H](OC(C)=O)C(=O)[C@]3(C)[C@@]1(C)C[C@H](OC(C)=O)C2=C(CCC=C(C)C)C(O)=O formation
2012-06-07 Added DEFINITION The chemical reactions and pathways resulting in the formation of helvolic acid.
2012-06-07 Added SYNONYM (2Z)-2-[(4alpha,5alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17Z)-6,16-diacetoxy-4,8,10,14-tetramethyl-3,7-dioxogon-1-en-17-ylidene]-6-methylhept-5-enoic acid biosynthetic process
2012-06-07 Added SYNONYM 16-(Acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid biosynthesis
2012-06-07 Added SYNONYM 16-(Acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid formation
2012-06-07 Added SYNONYM Fumigacin synthesis
2012-06-07 Added SYNONYM InChIKey=MDFZYGLOIJNNRM-OAJDADRGSA-N formation
2012-06-07 Added SYNONYM helvolic acid anabolism
2012-06-07 Added SYNONYM (4alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17beta)-6,16- bis(acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid anabolism
2012-06-07 Added SYNONYM (4alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17beta)-6,16- bis(acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid formation
2012-06-07 Added SYNONYM C33H44O8 biosynthesis
2012-06-07 Added SYNONYM InChI=1S/C33H44O8/c1-17(2)10-9-11-21(30(38)39)26-22-12-13-25-31(6)15-14-23(36)18(3)27(31)28(41-20(5)35)29(37)33(25,8)32(22,7)16-24(26)40-19(4)34/h10,14-15,18,22,24-25,27-28H,9,11-13,16H2,1-8H3,(H,38,39)/b26-21-/t18-,22+,24+,25+,27-,28+,31-,32+,33-/m1/s1 synthesis
2012-06-07 Added SYNONYM InChIKey=MDFZYGLOIJNNRM-OAJDADRGSA-N biosynthesis
2012-06-07 Added SYNONYM InChIKey=MDFZYGLOIJNNRM-OAJDADRGSA-N biosynthetic process
2012-06-07 Added SYNONYM 16-(Acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid anabolism
2012-06-07 Added SYNONYM C33H44O8 anabolism
2012-06-07 Added SYNONYM C33H44O8 biosynthetic process
2012-06-07 Added SYNONYM InChI=1S/C33H44O8/c1-17(2)10-9-11-21(30(38)39)26-22-12-13-25-31(6)15-14-23(36)18(3)27(31)28(41-20(5)35)29(37)33(25,8)32(22,7)16-24(26)40-19(4)34/h10,14-15,18,22,24-25,27-28H,9,11-13,16H2,1-8H3,(H,38,39)/b26-21-/t18-,22+,24+,25+,27-,28+,31-,32+,33-/m1/s1 biosynthetic process
2012-06-07 Added SYNONYM InChIKey=MDFZYGLOIJNNRM-OAJDADRGSA-N anabolism
2012-06-07 Added SYNONYM [H][C@@]12CC[C@@]3([H])[C@@]4(C)C=CC(=O)[C@@H](C)[C@]4([H])[C@H](OC(C)=O)C(=O)[C@]3(C)[C@@]1(C)C[C@H](OC(C)=O)C2=C(CCC=C(C)C)C(O)=O biosynthesis
2012-06-07 Added SYNONYM 16-(Acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid synthesis
2012-06-07 Added SYNONYM (4alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17beta)-6,16- bis(acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid biosynthetic process
2012-06-07 Added SYNONYM (4alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17beta)-6,16- bis(acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid synthesis
2012-06-07 Added SYNONYM 16-(Acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid biosynthetic process
2012-06-07 Added SYNONYM InChI=1S/C33H44O8/c1-17(2)10-9-11-21(30(38)39)26-22-12-13-25-31(6)15-14-23(36)18(3)27(31)28(41-20(5)35)29(37)33(25,8)32(22,7)16-24(26)40-19(4)34/h10,14-15,18,22,24-25,27-28H,9,11-13,16H2,1-8H3,(H,38,39)/b26-21-/t18-,22+,24+,25+,27-,28+,31-,32+,33-/m1/s1 anabolism
2012-06-07 Added SYNONYM InChI=1S/C33H44O8/c1-17(2)10-9-11-21(30(38)39)26-22-12-13-25-31(6)15-14-23(36)18(3)27(31)28(41-20(5)35)29(37)33(25,8)32(22,7)16-24(26)40-19(4)34/h10,14-15,18,22,24-25,27-28H,9,11-13,16H2,1-8H3,(H,38,39)/b26-21-/t18-,22+,24+,25+,27-,28+,31-,32+,33-/m1/s1 biosynthesis
2012-06-07 Added SYNONYM helvolic acid biosynthesis
2012-06-07 Added SYNONYM Fumigacin formation
2012-06-07 Added SYNONYM InChI=1S/C33H44O8/c1-17(2)10-9-11-21(30(38)39)26-22-12-13-25-31(6)15-14-23(36)18(3)27(31)28(41-20(5)35)29(37)33(25,8)32(22,7)16-24(26)40-19(4)34/h10,14-15,18,22,24-25,27-28H,9,11-13,16H2,1-8H3,(H,38,39)/b26-21-/t18-,22+,24+,25+,27-,28+,31-,32+,33-/m1/s1 formation
2012-06-07 Added SYNONYM [H][C@@]12CC[C@@]3([H])[C@@]4(C)C=CC(=O)[C@@H](C)[C@]4([H])[C@H](OC(C)=O)C(=O)[C@]3(C)[C@@]1(C)C[C@H](OC(C)=O)C2=C(CCC=C(C)C)C(O)=O anabolism
2012-06-07 Added SYNONYM (4alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17beta)-6,16- bis(acetyloxy)-3,7-dioxo-29-nordammara-1,17(20),24-trien-21-oic acid biosynthesis
2012-06-07 Added SYNONYM C33H44O8 formation
2012-06-07 Added SYNONYM C33H44O8 synthesis
2012-06-07 Added SYNONYM Fumigacin anabolism
2012-06-07 Added SYNONYM Fumigacin biosynthesis
2012-06-07 Added SYNONYM Fumigacin biosynthetic process
2012-06-07 Added SYNONYM InChIKey=MDFZYGLOIJNNRM-OAJDADRGSA-N synthesis
2012-06-07 Added SYNONYM [H][C@@]12CC[C@@]3([H])[C@@]4(C)C=CC(=O)[C@@H](C)[C@]4([H])[C@H](OC(C)=O)C(=O)[C@]3(C)[C@@]1(C)C[C@H](OC(C)=O)C2=C(CCC=C(C)C)C(O)=O biosynthetic process
2012-06-07 Added SYNONYM helvolic acid synthesis
2012-06-07 Added SYNONYM (2Z)-2-[(4alpha,5alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17Z)-6,16-diacetoxy-4,8,10,14-tetramethyl-3,7-dioxogon-1-en-17-ylidene]-6-methylhept-5-enoic acid anabolism
2012-06-07 Added SYNONYM (2Z)-2-[(4alpha,5alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17Z)-6,16-diacetoxy-4,8,10,14-tetramethyl-3,7-dioxogon-1-en-17-ylidene]-6-methylhept-5-enoic acid biosynthesis
2012-06-07 Added SYNONYM (2Z)-2-[(4alpha,5alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17Z)-6,16-diacetoxy-4,8,10,14-tetramethyl-3,7-dioxogon-1-en-17-ylidene]-6-methylhept-5-enoic acid formation
2012-06-07 Added SYNONYM (2Z)-2-[(4alpha,5alpha,6beta,8alpha,9beta,13alpha,14beta,16beta,17Z)-6,16-diacetoxy-4,8,10,14-tetramethyl-3,7-dioxogon-1-en-17-ylidene]-6-methylhept-5-enoic acid synthesis
2012-06-07 Added SYNONYM [H][C@@]12CC[C@@]3([H])[C@@]4(C)C=CC(=O)[C@@H](C)[C@]4([H])[C@H](OC(C)=O)C(=O)[C@]3(C)[C@@]1(C)C[C@H](OC(C)=O)C2=C(CCC=C(C)C)C(O)=O formation
2012-06-07 Added SYNONYM [H][C@@]12CC[C@@]3([H])[C@@]4(C)C=CC(=O)[C@@H](C)[C@]4([H])[C@H](OC(C)=O)C(=O)[C@]3(C)[C@@]1(C)C[C@H](OC(C)=O)C2=C(CCC=C(C)C)C(O)=O synthesis
2012-06-07 Added SYNONYM helvolic acid formation

Relationships

Timestamp Action Category Detail
2014-03-07 Added RELATION is a GO:0042181 (ketone biosynthetic process)
2014-01-16 Added RELATION is a GO:0072330 (monocarboxylic acid biosynthetic process)
2014-01-16 Deleted RELATION is a GO:0046394 (carboxylic acid biosynthetic process)
2012-10-19 Added RELATION is a GO:0044550 (secondary metabolite biosynthetic process)
2012-06-07 Added RELATION is a GO:1900810 (helvolic acid metabolic process)
2012-06-07 Added RELATION is a GO:0046394 (carboxylic acid biosynthetic process)
2012-06-07 Added RELATION is a GO:0006694 (steroid biosynthetic process)
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